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- W2123645242 abstract "High-quality polycrystalline samples of postperovskite type CaIr1−xPtxO3 solid solutions (x = 0.3, 0.5, 0.7) and CaIr0.5Rh0.5O3 have been synthesized at a pressure of 15 GPa, and their structures and properties are compared with those of CaIrO3. Substantial [100] grain growth is observed in all samples, leading to pronounced texture even in powdered materials. Small changes in the lattice constants and octahedral distortions are observed across the CaIr1−xPtxO3 series. CaIrO3 is semiconducting and shows temperature-independent paramagnetism and an ordered moment of 0.04 μB below a 108 K magnetic transition. Doping with Pt or Rh induces Curie−Weiss paramagnetism and suppresses the magnetic transition to zero for ∼40% Pt doping. The anisotropic structure and morphology of CaIrO3 combined with the Ir4+ spin−orbit coupling results in a large magnetic anisotropy constant of 1.77 × 106 J m−3, comparable to values for permanent magnet materials." @default.
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- W2123645242 date "2010-12-16" @default.
- W2123645242 modified "2023-09-27" @default.
- W2123645242 title "Tuning of Structure, Morphology and Magnetism in Postperovskite Oxide Solid Solutions" @default.
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- W2123645242 doi "https://doi.org/10.1021/cm102660q" @default.
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