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• W2123703185 abstract "Abstract Chlorination of C 100 fullerene with a mixture of VCl 4 and SbCl 5 afforded C 96 Cl 20 with a strongly unconventional structure. In contrast to the classical fullerenes containing only hexagonal and pentagonal rings, the C 96 cage contains three heptagonal rings and, therefore, should be classified as a fullerene with a nonclassical cage (NCC). There are several types of pentagon fusions in the C 96 cage including pentagon pairs and pentagon triples. The three‐step pathway from isolated‐pentagon‐rule (IPR) C 100 to C 96 (NCC‐3hp) includes two C 2 losses, which create two cage heptagons, and one Stone–Wales rotation under formation of the third heptagon. Structural reconstruction established C 100 isomer no. 18 from 450 topologically possible IPR isomers as the starting C 100 fullerene. Until now, no pristine C 100 isomers have been confirmed based on the experimental results." @default.
• W2123703185 created "2016-06-24" @default.
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• W2123703185 date "2014-01-29" @default.
• W2123703185 modified "2023-10-18" @default.
• W2123703185 title "Chlorination of IPR C₁₀₀Fullerene Affords Unconventional C₉₆Cl₂₀with a Nonclassical Cage Containing Three Heptagons" @default.
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• W2123703185 doi "https://doi.org/10.1002/anie.201310099" @default.
• W2123703185 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24474701" @default.
• W2123703185 hasPublicationYear "2014" @default.
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