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- W2123839314 abstract "Charge transfer in GaAs is analysed utilising our earlier precise and extensive X-ray diffraction data. The h + k + l = 4n + 2 structure factors are weak, quasi-forbidden with the constituent atoms of nearly equal but opposite scattering. The measured structure factors are all systematically larger than their calculated values over the entire range of sin θ/λ up to about 10 nm -1 . Moreover. they exhibit non-equivalence of inverse reflections with non-zero indices which can arise only from bonding distortion or anharmonicity. A model calculation for the charge transfer in bonding from the III to the V atom, described by a single parameter x, valid over the entire reciprocal space. is proposed and found to yield a precise estimate for x, namely 0.52(0.12) for GaAs (in electron units). This result is in good agreement with the earlier models, and indicates an appreciable core contribution to the charge transfer." @default.
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- W2123839314 date "1996-07-01" @default.
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- W2123839314 title "Charge transfer in the bonding of gaas" @default.
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- W2123839314 doi "https://doi.org/10.1002/pssb.2221960102" @default.
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