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- W2123908032 abstract "Novel unusually structured organic compounds can be made available with the aid of organometallic chemistry. A variety of typical examples are presented in this account where the unique stereoelectronic features of the bent metallocene bis(cyclopentadienyl)zirconium are used to stabilize uncommon coordination geometries of the element carbon. This includes internal ion pair phenomena and the electronic stabilization of planar-tetracoordinate carbon, examples of distorted C2v-methane derivatives and of unprecedented geometries of pentacoordinated carbon compounds. For many such systems their specific energetic stabilization was estimated from suitable experiments." @default.
- W2123908032 created "2016-06-24" @default.
- W2123908032 creator A5034807035 @default.
- W2123908032 date "1999-01-01" @default.
- W2123908032 modified "2023-09-30" @default.
- W2123908032 title "Using bent metallocenes for stabilizing unusual coordination geometries at carbon" @default.
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- W2123908032 doi "https://doi.org/10.1039/a708611c" @default.
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