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- W2124162643 abstract "Hydrazone 30, precursor of a taxoid C-ring, was synthesized in 7 steps from commercial 2-methyl-1,3-cyclohexanedione. An enantioselective approach to 30 was also investigated, using a reduction of diketone 11 with bakers’ yeast to introduce enantioselectivity. During the alkyne isomerization step, anionic cyclizations of alkoxides and enolates onto the triple bond were observed, and a thorough study of these reactions is reported here." @default.
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- W2124162643 date "2000-12-01" @default.
- W2124162643 modified "2023-09-25" @default.
- W2124162643 title "Alkyne Zip Reaction in the Synthesis of a Taxoid C-Ring" @default.
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- W2124162643 doi "https://doi.org/10.1002/1099-0690(200012)2000:24<4029::aid-ejoc4029>3.0.co;2-0" @default.
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