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- W2124197320 abstract "Mass spectrometric and weight loss measurements of the species effusing from a Knudsen cell containing GaAs were used to obtain vapor pressures over the temperature range 900–1200°K. The As2As4 ratio was observed in these measurements to be substantially larger than previously reported2.3 when precautions were taken to prevent the buildup of arsenic vapor in the mass spectrometer ionization chamber. A third law treatment of the data gave enthalpies for the reactions: GaAs(s)→ Ga(s) + 12As2(g) ΔH2980 = 44.9 kcal GaAs(s)→ Ga(s) + 14As4(g) ΔH2980 = 29.4 kcal 2As2(g) → As4(g) ΔH2980 = −62.5 kcal GaAs(s) → Ga(g) + As(g) ΔH2980 = 155 kcal These results were used to correct Thurmond's calculations of vapor pressures and activity coefficients along the GaAs liquidus.(1)" @default.
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- W2124197320 date "1967-11-01" @default.
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- W2124197320 title "Vapor pressures and phase equilibria in the GaAs system" @default.
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- W2124197320 doi "https://doi.org/10.1016/0022-3697(67)90251-x" @default.
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