Matches in SemOpenAlex for { <https://semopenalex.org/work/W2124232014> ?p ?o ?g. }
- W2124232014 endingPage "408" @default.
- W2124232014 startingPage "400" @default.
- W2124232014 abstract "Poly(styrene-co-ethyl acrylate) [P(St-co-EA)] with different ratios of St/EA was mixed with the small molecule 4,4′-thio-bis(6-tert-butyl-m-methyl phenol) (AO300) to investigate the influence of hydrogen bonding strength on the glass transition behavior. The glass transition temperature (Tg) linearly increased after adding AO300, and the slope value decreased with increased St/EA ratio. All lines could be extended to 62 °C, demonstrating that Tg of the small molecule in situ detected by the polymer chain was much higher than that by small molecule itself (29 °C). Fourier transform infrared spectroscopy analysis showed that the small molecules began to be self-associated at a concentration where the hydrogen bonded carbonyl ratio of the bulk polymer was approximately 0.5 and irrespective of the St/EA ratio. Above the critical loading, the mixture's Tg negatively deviated from the linearly extended lines because of self-association of the small molecules. The apparent Tg of AO300 was found to strongly depend on intermolecular hydrogen bonding number and strength. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015, 53, 400–408" @default.
- W2124232014 created "2016-06-24" @default.
- W2124232014 creator A5007113754 @default.
- W2124232014 creator A5023764890 @default.
- W2124232014 creator A5032902004 @default.
- W2124232014 creator A5037187271 @default.
- W2124232014 creator A5045375527 @default.
- W2124232014 date "2014-12-01" @default.
- W2124232014 modified "2023-10-16" @default.
- W2124232014 title "Small molecule-mediated glass transition of acrylic copolymers: Effect of hydrogen bonding strength on glass transition temperature" @default.
- W2124232014 cites W1975030247 @default.
- W2124232014 cites W1978572996 @default.
- W2124232014 cites W1979739098 @default.
- W2124232014 cites W1982311462 @default.
- W2124232014 cites W1985071287 @default.
- W2124232014 cites W1998366922 @default.
- W2124232014 cites W1998647396 @default.
- W2124232014 cites W2004094659 @default.
- W2124232014 cites W2004101375 @default.
- W2124232014 cites W2006747065 @default.
- W2124232014 cites W2017004908 @default.
- W2124232014 cites W2023633642 @default.
- W2124232014 cites W2026074179 @default.
- W2124232014 cites W2028534114 @default.
- W2124232014 cites W2030339761 @default.
- W2124232014 cites W2033855051 @default.
- W2124232014 cites W2035356948 @default.
- W2124232014 cites W2039740050 @default.
- W2124232014 cites W2040982169 @default.
- W2124232014 cites W2047948690 @default.
- W2124232014 cites W2057009283 @default.
- W2124232014 cites W2057771908 @default.
- W2124232014 cites W2064749237 @default.
- W2124232014 cites W2068850127 @default.
- W2124232014 cites W2072753467 @default.
- W2124232014 cites W2074293901 @default.
- W2124232014 cites W2080331283 @default.
- W2124232014 cites W2090685074 @default.
- W2124232014 cites W2092040054 @default.
- W2124232014 cites W2094208954 @default.
- W2124232014 cites W2094875280 @default.
- W2124232014 cites W2117441301 @default.
- W2124232014 cites W2119394605 @default.
- W2124232014 cites W2126922559 @default.
- W2124232014 cites W2131411000 @default.
- W2124232014 cites W2151228606 @default.
- W2124232014 cites W2163594599 @default.
- W2124232014 cites W2314521610 @default.
- W2124232014 cites W2321947895 @default.
- W2124232014 cites W2322086357 @default.
- W2124232014 cites W2329557602 @default.
- W2124232014 doi "https://doi.org/10.1002/polb.23642" @default.
- W2124232014 hasPublicationYear "2014" @default.
- W2124232014 type Work @default.
- W2124232014 sameAs 2124232014 @default.
- W2124232014 citedByCount "16" @default.
- W2124232014 countsByYear W21242320142015 @default.
- W2124232014 countsByYear W21242320142016 @default.
- W2124232014 countsByYear W21242320142018 @default.
- W2124232014 countsByYear W21242320142019 @default.
- W2124232014 countsByYear W21242320142020 @default.
- W2124232014 countsByYear W21242320142021 @default.
- W2124232014 countsByYear W21242320142022 @default.
- W2124232014 crossrefType "journal-article" @default.
- W2124232014 hasAuthorship W2124232014A5007113754 @default.
- W2124232014 hasAuthorship W2124232014A5023764890 @default.
- W2124232014 hasAuthorship W2124232014A5032902004 @default.
- W2124232014 hasAuthorship W2124232014A5037187271 @default.
- W2124232014 hasAuthorship W2124232014A5045375527 @default.
- W2124232014 hasConcept C112887158 @default.
- W2124232014 hasConcept C122865956 @default.
- W2124232014 hasConcept C127413603 @default.
- W2124232014 hasConcept C15920480 @default.
- W2124232014 hasConcept C159985019 @default.
- W2124232014 hasConcept C160892712 @default.
- W2124232014 hasConcept C166950319 @default.
- W2124232014 hasConcept C178790620 @default.
- W2124232014 hasConcept C185592680 @default.
- W2124232014 hasConcept C188027245 @default.
- W2124232014 hasConcept C192562407 @default.
- W2124232014 hasConcept C2777566558 @default.
- W2124232014 hasConcept C2779989194 @default.
- W2124232014 hasConcept C32909587 @default.
- W2124232014 hasConcept C42360764 @default.
- W2124232014 hasConcept C521977710 @default.
- W2124232014 hasConceptScore W2124232014C112887158 @default.
- W2124232014 hasConceptScore W2124232014C122865956 @default.
- W2124232014 hasConceptScore W2124232014C127413603 @default.
- W2124232014 hasConceptScore W2124232014C15920480 @default.
- W2124232014 hasConceptScore W2124232014C159985019 @default.
- W2124232014 hasConceptScore W2124232014C160892712 @default.
- W2124232014 hasConceptScore W2124232014C166950319 @default.
- W2124232014 hasConceptScore W2124232014C178790620 @default.
- W2124232014 hasConceptScore W2124232014C185592680 @default.
- W2124232014 hasConceptScore W2124232014C188027245 @default.
- W2124232014 hasConceptScore W2124232014C192562407 @default.
- W2124232014 hasConceptScore W2124232014C2777566558 @default.
- W2124232014 hasConceptScore W2124232014C2779989194 @default.