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• W2124307215 endingPage "4685" @default.
• W2124307215 startingPage "4678" @default.
• W2124307215 abstract "Two new tetranuclear chalcocyanide cluster complexes, [{Mn(saloph)H2O}4Re4Q4(CN)12]⋅4 CH3OH⋅ 8 H2O (saloph=N,N′-o-phenylenebis(salicylidenaminato), Q=Se (1-Se), Te (2-Te)), have been synthesized by the diffusion of a methanolic solution of [PPh4]4[Re4Q4(CN)12] into a methanolic solution of [Mn(saloph)]+. The structure of 2-Te has been determined by X-ray crystallography. These rhenium cluster-supported [MnIII(saloph)] complexes have been found to efficiently catalyze a wide range of olefin epoxidations under mild experimental conditions in the presence of meta-chloroperbenzoic acid (mCPBA). Olefin epoxidation by these catalysts is proposed to involve the multiple active oxidants MnVO, MnIVO, and MnIIIOOC(O)R. Evidence in support of this interpretation has been derived from reactivity and Hammett studies, H218O-exchange experiments, and the use of peroxyphenylacetic acid as a mechanistic probe. Moreover, it has been observed that the participation of MnVO, MnIVO, and MnIIIOOC(O)R can be controlled by changing the substrate concentration. This mechanism provides the greatest congruity with related oxidation reactions that employ certain Mn complexes as catalysts." @default.
• W2124307215 created "2016-06-24" @default.
• W2124307215 creator A5002403713 @default.
• W2124307215 creator A5021787719 @default.
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• W2124307215 creator A5056506851 @default.
• W2124307215 creator A5070668206 @default.
• W2124307215 creator A5084370542 @default.
• W2124307215 creator A5086757509 @default.
• W2124307215 creator A5088131160 @default.
• W2124307215 creator A5090364028 @default.
• W2124307215 date "2010-04-19" @default.
• W2124307215 modified "2023-10-01" @default.
• W2124307215 title "Efficient Olefin Epoxidation by Robust Re₄Cluster-Supported Mn^IIIComplexes with Peracids: Evidence of Simultaneous Operation of Multiple Active Oxidant Species, Mn^VO, Mn^IVO, and Mn^IIIOOC(O)R" @default.
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