Matches in SemOpenAlex for { <https://semopenalex.org/work/W2124312258> ?p ?o ?g. }
- W2124312258 endingPage "5536" @default.
- W2124312258 startingPage "5526" @default.
- W2124312258 abstract "Abstract A family of chiral (cyclopentadienone)iron complexes, featuring an ( R )‐BINOL‐derived backbone, and their application in the asymmetric hydrogenation of ketones are described. The complexes differ from each other in the substituents at the 3,3′‐positions of the binaphthyl residue (H, OH, OR, OCOR, OSO 2 R) or at the 2,5‐positions of the cyclopentadienone ring [trimethylsilyl (TMS) or Ph]. Remarkably, eight precatalysts with different 3,3′‐binaphthyl substitution [( R )‐ 1c – 1j ] were synthesized from a common parent complex [( R )‐ 1b ] through direct functional group interconversion reactions of the complexes. The 3,3′‐(bis)methoxy‐substituted precatalyst ( R )‐ 1b gave the best catalytic performance, and its application scope was assessed in the hydrogenation of several ketones. The observed ee values (up to 77 %) are much higher than those previously reported for other chiral (cyclopentadienone)iron complexes." @default.
- W2124312258 created "2016-06-24" @default.
- W2124312258 creator A5006185181 @default.
- W2124312258 creator A5007595224 @default.
- W2124312258 creator A5016113159 @default.
- W2124312258 creator A5019442123 @default.
- W2124312258 creator A5024472505 @default.
- W2124312258 creator A5031541703 @default.
- W2124312258 creator A5039707847 @default.
- W2124312258 creator A5059653647 @default.
- W2124312258 creator A5089720205 @default.
- W2124312258 date "2015-07-23" @default.
- W2124312258 modified "2023-10-10" @default.
- W2124312258 title "Synthesis of (<i>R</i>)-BINOL-Derived (Cyclopentadienone)iron Complexes and Their Application in the Catalytic Asymmetric Hydrogenation of Ketones" @default.
- W2124312258 cites W1752709686 @default.
- W2124312258 cites W1917522901 @default.
- W2124312258 cites W1964892471 @default.
- W2124312258 cites W1965085647 @default.
- W2124312258 cites W1970225878 @default.
- W2124312258 cites W1970847965 @default.
- W2124312258 cites W1971643970 @default.
- W2124312258 cites W1974421682 @default.
- W2124312258 cites W1976278898 @default.
- W2124312258 cites W1983738366 @default.
- W2124312258 cites W1994565612 @default.
- W2124312258 cites W1997721562 @default.
- W2124312258 cites W1999134339 @default.
- W2124312258 cites W2005244766 @default.
- W2124312258 cites W2011980221 @default.
- W2124312258 cites W2012092497 @default.
- W2124312258 cites W2020769232 @default.
- W2124312258 cites W2032294243 @default.
- W2124312258 cites W2032997390 @default.
- W2124312258 cites W2033266955 @default.
- W2124312258 cites W2034816859 @default.
- W2124312258 cites W2039619076 @default.
- W2124312258 cites W2042926180 @default.
- W2124312258 cites W2050979151 @default.
- W2124312258 cites W2052462458 @default.
- W2124312258 cites W2061630997 @default.
- W2124312258 cites W2065578557 @default.
- W2124312258 cites W2069607377 @default.
- W2124312258 cites W2069702158 @default.
- W2124312258 cites W2070263264 @default.
- W2124312258 cites W2074463764 @default.
- W2124312258 cites W2080766536 @default.
- W2124312258 cites W2081890623 @default.
- W2124312258 cites W2082114639 @default.
- W2124312258 cites W2085595472 @default.
- W2124312258 cites W2094891626 @default.
- W2124312258 cites W2095417590 @default.
- W2124312258 cites W2096285356 @default.
- W2124312258 cites W2103029770 @default.
- W2124312258 cites W2106346485 @default.
- W2124312258 cites W2108306229 @default.
- W2124312258 cites W2115592585 @default.
- W2124312258 cites W2115809286 @default.
- W2124312258 cites W2116032369 @default.
- W2124312258 cites W2116784815 @default.
- W2124312258 cites W2118790859 @default.
- W2124312258 cites W2125845584 @default.
- W2124312258 cites W2129249714 @default.
- W2124312258 cites W2135072167 @default.
- W2124312258 cites W2136950527 @default.
- W2124312258 cites W2146165919 @default.
- W2124312258 cites W2149148003 @default.
- W2124312258 cites W2150463228 @default.
- W2124312258 cites W2152015484 @default.
- W2124312258 cites W2155974810 @default.
- W2124312258 cites W2162047307 @default.
- W2124312258 cites W2169577643 @default.
- W2124312258 cites W2170402032 @default.
- W2124312258 cites W2312862192 @default.
- W2124312258 cites W2314745415 @default.
- W2124312258 cites W2325397456 @default.
- W2124312258 cites W2327379756 @default.
- W2124312258 cites W2327873646 @default.
- W2124312258 cites W2330243859 @default.
- W2124312258 cites W2541483410 @default.
- W2124312258 cites W2950652580 @default.
- W2124312258 cites W4242253060 @default.
- W2124312258 doi "https://doi.org/10.1002/ejoc.201500796" @default.
- W2124312258 hasPublicationYear "2015" @default.
- W2124312258 type Work @default.
- W2124312258 sameAs 2124312258 @default.
- W2124312258 citedByCount "43" @default.
- W2124312258 countsByYear W21243122582016 @default.
- W2124312258 countsByYear W21243122582017 @default.
- W2124312258 countsByYear W21243122582018 @default.
- W2124312258 countsByYear W21243122582019 @default.
- W2124312258 countsByYear W21243122582020 @default.
- W2124312258 countsByYear W21243122582021 @default.
- W2124312258 countsByYear W21243122582022 @default.
- W2124312258 countsByYear W21243122582023 @default.
- W2124312258 crossrefType "journal-article" @default.
- W2124312258 hasAuthorship W2124312258A5006185181 @default.
- W2124312258 hasAuthorship W2124312258A5007595224 @default.
- W2124312258 hasAuthorship W2124312258A5016113159 @default.