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• W2124314575 startingPage "015303" @default.
• W2124314575 abstract "Abstract A colossal permittivity ceramic material, Ca 2 TiCrO 6 , was successfully synthesized by the conventional solid-state reaction, and was characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), x-ray photoemission spectroscopy (XPS) and x-ray diffraction (XRD). Rietveld refinement of XRD data indicated that the material crystallized in orthorhombic structure with space group pbnm . SEM displayed Ca 2 TiCrO 6 ceramic grains packed uniformly with the size range 5–20 µ m. XPS analyses indicated that elemental chromium and titanium of the material were in mixed valence. The corresponding dielectric property was tested in the frequency range 1 kHz–1 MHz and the temperature range 213–453 K, and the ceramics exhibited a relaxation-like dielectric behaviour. Importantly, the permittivity of Ca 2 TiCrO 6 could reach 80 000 at 298 K (100 Hz) and was maintained at 40 000 up to 398 K at 1 MHz, which could be attributed to the ion disorder and mixed valence of Cr 3+ /Cr 6+ and Ti 3+ /Ti 4+ ." @default.
• W2124314575 created "2016-06-24" @default.
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• W2124314575 date "2012-11-27" @default.
• W2124314575 modified "2023-09-30" @default.
• W2124314575 title "Structure and colossal dielectric permittivity of Ca₂TiCrO₆ ceramics" @default.
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• W2124314575 doi "https://doi.org/10.1088/0022-3727/46/1/015303" @default.
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