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- W2124407664 abstract "An efficient and practical method for the synthesis of unsymmetric benzils from readily available β-ketoaldehydes has been developed. Various unsymmetric 1,2-diaryldiketones bearing functional groups have been obtained in good to excellent yields under mild reaction conditions. A plausible mechanism was proposed, and α,α-dichloroketone was considered as the key intermediate. The generation of α,α-dichloroketones from β-ketoaldehydes may undergo the following steps: (1) oxidation by sodium hypochlorite, (2) decarboxylation, and (3) chlorination by Cl2 generated from sodium hypochlorite." @default.
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- W2124407664 date "2014-01-29" @default.
- W2124407664 modified "2023-09-26" @default.
- W2124407664 title "Practical Approach for Preparation of Unsymmetric Benzils from β-Ketoaldehydes" @default.
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- W2124407664 doi "https://doi.org/10.1021/ol403762e" @default.
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