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• W2124453430 abstract "Single-handed PQXphos, i.e., helical poly(quinoxaline-2,3-diyl)s bearing diarylphosphino pendant groups, served as remarkable chiral ligands in palladium-catalyzed asymmetric hydrosilylation of styrenes and asymmetric biaryl synthesis by Suzuki–Miyaura coupling, affording up to 98 % enantiomeric excess (e.e.) in both reactions. A palladium complex of high-molecular-weight variant (1000mer) of PQXphos could be reused eight times by virtue of the formation of an insoluble polymer complex. PQXphos underwent solvent-dependent inversion of the helical sense, enabling production of either of two enantiomeric products using a single PQXphos." @default.
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• W2124453430 date "2012-02-03" @default.
• W2124453430 modified "2023-10-16" @default.
• W2124453430 title "Catalytic asymmetric synthesis using chirality-switchable helical polymer as a chiral ligand" @default.
• W2124453430 cites W2056344912 @default.
• W2124453430 cites W2092687731 @default.
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• W2124453430 doi "https://doi.org/10.1351/pac-con-11-08-23" @default.
• W2124453430 hasPublicationYear "2012" @default.
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