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- W2124501786 abstract "We report results of detailed studies on the underpotential deposition of lead (Pb UPD) and effects of specifically adsorbed halide anions on the UPD reaction at polycrystalline gold electrodes employing real-time staircase cyclic voltammetry Fourier transform electrochemical impedance spectroscopy (SCV-FTEIS). Potential shifts observed during the Pb UPD in the presence of halide ions are partially attributed to the chemical interaction of halide ions with Pb2+ as well as the physical obstruction by the preadsorbed halide ions. More importantly, the presorbed halides, on the top of which Pb2+ ions are adsorbed, form a pseudocapacitor on the gold surface, and its electrical discharge leads to the Pb UPD. Real-time SCV-FTEIS measurements in a chloride solution without Pb2+ reveal that the voltammetric currents arise from charging both the double-layer and pseudocapacitors formed due to the presorption of halide ions at the surface, indicating that the capacitors formed upon adsorption of halide ions on the electrode surface play a critical role in the Pb UPD." @default.
- W2124501786 created "2016-06-24" @default.
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- W2124501786 date "2008-10-01" @default.
- W2124501786 modified "2023-09-27" @default.
- W2124501786 title "Real-Time Staircase Cyclic Voltammetry Fourier Transform Electrochemical Impedance Spectroscopic Studies on Underpotential Deposition of Lead on Gold" @default.
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- W2124501786 doi "https://doi.org/10.1021/jp805960j" @default.
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