FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2124554031> ?p ?o ?g. }

• W2124554031 endingPage "553" @default.
• W2124554031 startingPage "543" @default.
• W2124554031 abstract "ABSTRACT The reactivity of few novel high‐spin Fe(II) complexes of Schiff base ligands derived from 2‐hydroxynaphthaldehyde and some variety of amino acids with the OH − ion has been examined in an aqueous mixture at the temperature range from 10 to 40°C. Based on the kinetic investigations, the rate law and a plausible mechanism were proposed and discussed. The general rate equation was suggested as follows: rate = k obs [complex], where k obs. = k 1 + k 2 [OH − ]. Base‐catalyzed hydrolysis kinetic measurements imply pseudo–first‐order doubly stage rates due the presence of mer‐ and fac‐isomers. The observed rate constants k obs are correlated with the effect of substituent R in the structure of the ligands. From the effect of temperature on the rate base hydrolysis reaction, various thermodynamic parameters were evaluated. The evaluated rate constants and activation parameters are in a good agreement with the stability constants of the investigated complexes. Moreover, the reactivity of the investigated complexes toward DNA was examined and found to be in a good agreement with the reported binding constants." @default.
• W2124554031 created "2016-06-24" @default.
• W2124554031 creator A5023411968 @default.
• W2124554031 creator A5035069908 @default.
• W2124554031 creator A5049574319 @default.
• W2124554031 creator A5061884382 @default.
• W2124554031 date "2014-07-25" @default.
• W2124554031 modified "2023-10-05" @default.
• W2124554031 title "Reactivity Trends and Kinetic Inspection of Hydroxide Ion Attack and DNA Interaction on Some Pharmacologically Active Agents of Fe(II) Amino Acid Schiff Base Complexes at Different Temperatures" @default.
• W2124554031 cites W110140261 @default.
• W2124554031 cites W1967552325 @default.
• W2124554031 cites W1971404196 @default.
• W2124554031 cites W1971424567 @default.
• W2124554031 cites W1974743764 @default.
• W2124554031 cites W1975399345 @default.
• W2124554031 cites W1981964398 @default.
• W2124554031 cites W1984189967 @default.
• W2124554031 cites W1990210215 @default.
• W2124554031 cites W1997411079 @default.
• W2124554031 cites W2003900288 @default.
• W2124554031 cites W2006111853 @default.
• W2124554031 cites W2007434947 @default.
• W2124554031 cites W2014920636 @default.
• W2124554031 cites W2015864415 @default.
• W2124554031 cites W2021643804 @default.
• W2124554031 cites W2027636480 @default.
• W2124554031 cites W2041415729 @default.
• W2124554031 cites W2045719132 @default.
• W2124554031 cites W2046421625 @default.
• W2124554031 cites W2060673562 @default.
• W2124554031 cites W2073855185 @default.
• W2124554031 cites W2074063767 @default.
• W2124554031 cites W2075455395 @default.
• W2124554031 cites W2080767746 @default.
• W2124554031 cites W2092902954 @default.
• W2124554031 cites W2322127364 @default.
• W2124554031 cites W49113959 @default.
• W2124554031 doi "https://doi.org/10.1002/kin.20869" @default.
• W2124554031 hasPublicationYear "2014" @default.
• W2124554031 type Work @default.
• W2124554031 sameAs 2124554031 @default.
• W2124554031 citedByCount "12" @default.
• W2124554031 countsByYear W21245540312014 @default.
• W2124554031 countsByYear W21245540312015 @default.
• W2124554031 countsByYear W21245540312016 @default.
• W2124554031 countsByYear W21245540312017 @default.
• W2124554031 countsByYear W21245540312020 @default.
• W2124554031 countsByYear W21245540312021 @default.
• W2124554031 crossrefType "journal-article" @default.
• W2124554031 hasAuthorship W2124554031A5023411968 @default.
• W2124554031 hasAuthorship W2124554031A5035069908 @default.
• W2124554031 hasAuthorship W2124554031A5049574319 @default.
• W2124554031 hasAuthorship W2124554031A5061884382 @default.
• W2124554031 hasConcept C121332964 @default.
• W2124554031 hasConcept C134306372 @default.
• W2124554031 hasConcept C135889238 @default.
• W2124554031 hasConcept C142724271 @default.
• W2124554031 hasConcept C145148216 @default.
• W2124554031 hasConcept C147597530 @default.
• W2124554031 hasConcept C147789679 @default.
• W2124554031 hasConcept C148898269 @default.
• W2124554031 hasConcept C178790620 @default.
• W2124554031 hasConcept C179104552 @default.
• W2124554031 hasConcept C184651966 @default.
• W2124554031 hasConcept C185592680 @default.
• W2124554031 hasConcept C204787440 @default.
• W2124554031 hasConcept C2775896084 @default.
• W2124554031 hasConcept C2776428424 @default.
• W2124554031 hasConcept C2776910235 @default.
• W2124554031 hasConcept C2778689049 @default.
• W2124554031 hasConcept C33923547 @default.
• W2124554031 hasConcept C42058472 @default.
• W2124554031 hasConcept C62520636 @default.
• W2124554031 hasConcept C71240020 @default.
• W2124554031 hasConcept C71924100 @default.
• W2124554031 hasConcept C93391505 @default.
• W2124554031 hasConcept C94412978 @default.
• W2124554031 hasConceptScore W2124554031C121332964 @default.
• W2124554031 hasConceptScore W2124554031C134306372 @default.
• W2124554031 hasConceptScore W2124554031C135889238 @default.
• W2124554031 hasConceptScore W2124554031C142724271 @default.
• W2124554031 hasConceptScore W2124554031C145148216 @default.
• W2124554031 hasConceptScore W2124554031C147597530 @default.
• W2124554031 hasConceptScore W2124554031C147789679 @default.
• W2124554031 hasConceptScore W2124554031C148898269 @default.
• W2124554031 hasConceptScore W2124554031C178790620 @default.
• W2124554031 hasConceptScore W2124554031C179104552 @default.
• W2124554031 hasConceptScore W2124554031C184651966 @default.
• W2124554031 hasConceptScore W2124554031C185592680 @default.
• W2124554031 hasConceptScore W2124554031C204787440 @default.
• W2124554031 hasConceptScore W2124554031C2775896084 @default.
• W2124554031 hasConceptScore W2124554031C2776428424 @default.
• W2124554031 hasConceptScore W2124554031C2776910235 @default.
• W2124554031 hasConceptScore W2124554031C2778689049 @default.
• W2124554031 hasConceptScore W2124554031C33923547 @default.
• W2124554031 hasConceptScore W2124554031C42058472 @default.
• W2124554031 hasConceptScore W2124554031C62520636 @default.
• W2124554031 hasConceptScore W2124554031C71240020 @default.

• next