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• W2124561851 abstract "The transformation of MnII glycolates (glc) between the three-dimensional coordination polymer [Mn(glc)2]n (1) and discrete mononuclear phase [Mn(glc)2(H2O)2] (2) can be reversibly switched by water molecules, which dramatically change the magnetocaloric effect (MCE) of MnII glycolates from the maximum of 6.9 J kg−1 K−1 in 1 to 60.3 J kg−1 K−1 in 2. This case example reveals that the effect of magnetic coupling on MCE plays a dominant role over that of other factors such as magnetic density for 3d-type magnetic refrigerants." @default.
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• W2124561851 date "2014-02-13" @default.
• W2124561851 modified "2023-10-01" @default.
• W2124561851 title "Switching of the Magnetocaloric Effect of Mn^IIGlycolate by Water Molecules" @default.
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• W2124561851 doi "https://doi.org/10.1002/chem.201304423" @default.
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