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- W2124625642 abstract "In the present work we consider the dynamics of freely translating and rotating diblock (A−B), Gaussian copolymers, in dilute solutions. Using the previously developed multiple scattering technique [J. Chem. Phys. 1978, 69, 2657, 2088; 1979, 70, 5875 (refs 1−3)]applied to the study of suspensions of spheres and polymerswe have computed the diffusion and the friction coefficients DAB and ζAB, respectively, and the change δηAB in the viscosity of the solution as functions of x = NA/N and t = lB/lA, where NA and N are the number of segments of the A block and of the whole copolymer, respectively, and lA and lB are the Kuhn lengths of the A and B blocks. Specific regimes that maximize the difference between the diffusion constants of copolymers with distinct t values, which lead to increasing the efficiency of separation processes, have been identified." @default.
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- W2124625642 date "1997-10-01" @default.
- W2124625642 modified "2023-10-08" @default.
- W2124625642 title "Dynamics of Diblock Copolymers in Dilute Solutions" @default.
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- W2124625642 doi "https://doi.org/10.1021/ma970339e" @default.
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