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- W2124741607 abstract "A practical method of olefin epoxidation was developed by combining FeCl3·6H2O and 1-methylimidazole in acetone using H2O2 as the terminal oxidant. This system showed very good reactivity toward epoxidation of both terminal and substituted alkenes. The use of tridentate and tetradentate amine-bis(phenolate) ligands as additives was also examined. Modest improvement in selectivity was achieved if a bulky tridentate ligand was used. Generally, however, the simple catalyst system involving ferric chloride, 1-methylimidazole and dilute H2O2 in acetone proved most successful in achieving good to excellent yields of epoxide products for a number of substrates, including aromatic and aliphatic alkenes." @default.
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- W2124741607 date "2011-01-01" @default.
- W2124741607 modified "2023-09-30" @default.
- W2124741607 title "Iron-catalyzed epoxidation of olefins using hydrogen peroxide" @default.
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- W2124741607 doi "https://doi.org/10.1039/c0gc00943a" @default.
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