FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2124937035> ?p ?o ?g. }

• W2124937035 endingPage "11780" @default.
• W2124937035 startingPage "11771" @default.
• W2124937035 abstract "The electronic structure of the mononuclear hydroxo MO3(OH)- and methoxo MO3(OCH3)- Group 6 oxometalate anions (M = Cr, Mo, and W) were examined by photodetachment photoelectron spectroscopy and electronic structure calculations at the density functional and CCSD(T) levels of theory. All of the anions exhibited high electron binding energies (>4.9 eV), with the lowest-energy detachment features arising from oxygen 2p-based orbitals. The combined experimental and theoretical results allowed the change in molecular orbital energy levels to be investigated as a function of metal (Cr, Mo, or W) and ligand (−OH, −OCH3). A number of fundamental thermodynamic properties of the anions and corresponding neutrals were predicted on the basis of the theoretical calculations. The calculations indicate high O−H bond dissociation energies for MO2(OR)(O−H) (R = H, CH3) and MO3(O−H), consistent with their high Brønsted acidities (just below that of H2SO4 in the gas phase) and the high ionization energies of their conjugate base anions. This suggests that the corresponding radicals should readily abstract H atoms from organic molecules." @default.
• W2124937035 created "2016-06-24" @default.
• W2124937035 creator A5020631828 @default.
• W2124937035 creator A5041685367 @default.
• W2124937035 creator A5053967127 @default.
• W2124937035 creator A5054206190 @default.
• W2124937035 creator A5062786033 @default.
• W2124937035 creator A5089126712 @default.
• W2124937035 date "2005-12-01" @default.
• W2124937035 modified "2023-10-17" @default.
• W2124937035 title "Electronic Structure of the Hydroxo and Methoxo Oxometalate Anions MO₃(OH)^- and MO₃(OCH₃)^- (M = Cr, Mo, and W)" @default.
• W2124937035 cites W1552285761 @default.
• W2124937035 cites W1563112153 @default.
• W2124937035 cites W1964069416 @default.
• W2124937035 cites W1965861470 @default.
• W2124937035 cites W1966792574 @default.
• W2124937035 cites W1970300747 @default.
• W2124937035 cites W1973427525 @default.
• W2124937035 cites W1976828279 @default.
• W2124937035 cites W1979590214 @default.
• W2124937035 cites W1982873306 @default.
• W2124937035 cites W1984599229 @default.
• W2124937035 cites W1993383767 @default.
• W2124937035 cites W1993638302 @default.
• W2124937035 cites W1997770065 @default.
• W2124937035 cites W1998732907 @default.
• W2124937035 cites W2002194503 @default.
• W2124937035 cites W2010912461 @default.
• W2124937035 cites W2012458244 @default.
• W2124937035 cites W2029836941 @default.
• W2124937035 cites W2030503311 @default.
• W2124937035 cites W2031240265 @default.
• W2124937035 cites W2034417515 @default.
• W2124937035 cites W2037335319 @default.
• W2124937035 cites W2038767330 @default.
• W2124937035 cites W2041583830 @default.
• W2124937035 cites W2041591938 @default.
• W2124937035 cites W2049079467 @default.
• W2124937035 cites W2053263196 @default.
• W2124937035 cites W2054707726 @default.
• W2124937035 cites W2059982628 @default.
• W2124937035 cites W2066532108 @default.
• W2124937035 cites W2067541410 @default.
• W2124937035 cites W2069006374 @default.
• W2124937035 cites W2072829312 @default.
• W2124937035 cites W2073753357 @default.
• W2124937035 cites W2074690741 @default.
• W2124937035 cites W2076578471 @default.
• W2124937035 cites W2085966856 @default.
• W2124937035 cites W2089297195 @default.
• W2124937035 cites W2092930273 @default.
• W2124937035 cites W2094550967 @default.
• W2124937035 cites W2095339520 @default.
• W2124937035 cites W2097739292 @default.
• W2124937035 cites W2099773424 @default.
• W2124937035 cites W2105722596 @default.
• W2124937035 cites W2117894566 @default.
• W2124937035 cites W2130046292 @default.
• W2124937035 cites W2143619709 @default.
• W2124937035 cites W2143981217 @default.
• W2124937035 cites W2145341709 @default.
• W2124937035 cites W2163746642 @default.
• W2124937035 cites W2167766581 @default.
• W2124937035 cites W2169977805 @default.
• W2124937035 cites W2492653521 @default.
• W2124937035 cites W2951921065 @default.
• W2124937035 cites W3105938624 @default.
• W2124937035 cites W3138466031 @default.
• W2124937035 cites W3139469897 @default.
• W2124937035 doi "https://doi.org/10.1021/jp054666x" @default.
• W2124937035 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16366627" @default.
• W2124937035 hasPublicationYear "2005" @default.
• W2124937035 type Work @default.
• W2124937035 sameAs 2124937035 @default.
• W2124937035 citedByCount "15" @default.
• W2124937035 countsByYear W21249370352013 @default.
• W2124937035 countsByYear W21249370352014 @default.
• W2124937035 countsByYear W21249370352016 @default.
• W2124937035 countsByYear W21249370352017 @default.
• W2124937035 crossrefType "journal-article" @default.
• W2124937035 hasAuthorship W2124937035A5020631828 @default.
• W2124937035 hasAuthorship W2124937035A5041685367 @default.
• W2124937035 hasAuthorship W2124937035A5053967127 @default.
• W2124937035 hasAuthorship W2124937035A5054206190 @default.
• W2124937035 hasAuthorship W2124937035A5062786033 @default.
• W2124937035 hasAuthorship W2124937035A5089126712 @default.
• W2124937035 hasConcept C102931765 @default.
• W2124937035 hasConcept C121332964 @default.
• W2124937035 hasConcept C139066938 @default.
• W2124937035 hasConcept C139358910 @default.
• W2124937035 hasConcept C145148216 @default.
• W2124937035 hasConcept C147192597 @default.
• W2124937035 hasConcept C147597530 @default.
• W2124937035 hasConcept C147789679 @default.
• W2124937035 hasConcept C152365726 @default.
• W2124937035 hasConcept C175708663 @default.
• W2124937035 hasConcept C178790620 @default.
• W2124937035 hasConcept C184779094 @default.

• next