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- W2125102654 abstract "Highly efficient catalytic asymmetric cyanoethoxycarbonylation of aldehydes was achieved by 10 mol % cinchonine with 10 mol % heterometallic (S)-aluminum lithium bis(binaphthoxide), which gave the cyanohydrins ethyl carbonates in excellent isolated yields (up to 99 %) with moderate to high enantioselectivities (up to 95 % ee) under mild conditions (at −20 °C). Especially, the solid aluminum lithium bis(binaphthoxide) free of tetrahydrofuran was obtained by a new procedure using (S)-bi(2-naphthol), aluminum isopropoxide and n-butyllithium in dichloromethane, which was insensitive to air and moisture and was very convenient to store and use. A catalytic cycle based on experimental phenomena was proposed to explain the nature of the asymmetric induction." @default.
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- W2125102654 date "2007-02-05" @default.
- W2125102654 modified "2023-10-15" @default.
- W2125102654 title "Asymmetric Cyanoethoxycarbonylation of Aldehydes Catalyzed by Heterobimetallic Aluminum Lithium Bis(binaphthoxide) and Cinchonine" @default.
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- W2125102654 doi "https://doi.org/10.1002/adsc.200600336" @default.
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