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- W2125282956 abstract "A highly efficient asymmetric dearomatization of indoles was realized through a cascade reaction between 2-isocyanoethylindole and alkylidene malonates catalyzed by a chiral N,N′-dioxide/MgII catalyst. Fused polycyclic indolines containing three stereocenters were afforded in good yields with excellent diastereo- and enantioselectivities through a Michael/Friedel–Crafts/Mannich cascade. When 2-substituted 2-isocyanoethylindoles were used, spiroindoline derivatives were obtained through a Michael/Friedel–Crafts reaction." @default.
- W2125282956 created "2016-06-24" @default.
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- W2125282956 date "2015-02-03" @default.
- W2125282956 modified "2023-10-03" @default.
- W2125282956 title "Asymmetric Dearomatization of Indoles through a Michael/Friedel-Crafts-Type Cascade To Construct Polycyclic Spiroindolines" @default.
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- W2125282956 doi "https://doi.org/10.1002/anie.201410814" @default.
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