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• W2125291318 abstract "A novel selective route to 1,1-bis(silyl)-1-alkenes has been developed. Sequential one-pot silylative coupling exo-cyclization of 1,2-bis(dimethylvinylsiloxy)ethane followed by the reaction with Grignard reagents leads to the desired 1,1-bis(silyl)ethenes, which are then efficiently coupled in the presence of silver nitrate and palladium acetate with aryl or alkenyl idodides to give the corresponding 1,1-bis(silyl)-2-arylethenes or 1,1,4-trisubstituted 1,3-butadienes with high yield." @default.
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• W2125291318 date "2006-09-23" @default.
• W2125291318 modified "2023-10-09" @default.
• W2125291318 title "A New Selective Approach to 1,1-Bis(silyl)-2-arylethenes and 1,1-Bis(silyl)-1,3-butadienes via Sequential Silylative Coupling−Heck Coupling Reactions" @default.
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• W2125291318 doi "https://doi.org/10.1021/jo0616254" @default.
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