FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2125341423> ?p ?o ?g. }

• W2125341423 endingPage "2940" @default.
• W2125341423 startingPage "2940" @default.
• W2125341423 abstract "Photoinduced charge separation processes of three-layer supramolecular hybrids, fullerene–porphyrin–SWCNT, which are constructed from semiconducting (7,6)- and (6,5)-enriched SWCNTs and self-assembled via π–π interacting long alkyl chain substituted porphyrins (tetrakis(4-dodecyloxyphenyl)porphyrins; abbreviated as MP(alkyl)4) (M = Zn and H2), to which imidazole functionalized fullerene[60] (C60Im) is coordinated, have been investigated in organic solvents. The intermolecular alkyl–π and π–π interactions between the MP(alkyl)4 and SWCNTs, in addition, coordination between C60Im and Zn ion in the porphyrin cavity are visualized using DFT calculations at the B3LYP/3-21G(*) level, predicting donor–acceptor interactions between them in the ground and excited states. The donor–acceptor nanohybrids thus formed are characterized by TEM imaging, steady-state absorption and fluorescence spectra. The time-resolved fluorescence studies of MP(alkyl)4 in two-layered nanohybrids (MP(alkyl)4/SWCNT) revealed efficient quenching of the singlet excited states of MP(alkyl)4 (1MP*(alkyl)4) with the rate constants of charge separation (kCS) in the range of (1–9) × 109 s−1. A nanosecond transient absorption technique confirmed the electron transfer products, MP˙+(alkyl)4/SWCNT˙− and/or MP˙−(alkyl)4/SWCNT˙+ for the two-layer nanohybrids. Upon further coordination of C60Im to ZnP, acceleration of charge separation via1ZnP* in C60Im→ZnP(alkyl)4/SWCNT is observed to form C60˙−Im→ZnP˙+(alkyl)4/SWCNT and C60˙−Im→ZnP(alkyl)4/SWCNT˙+ charge separated states as supported by the transient absorption spectra. These characteristic absorptions decay with rate constants due to charge recombination (kCR) in the range of (6–10) × 106 s−1, corresponding to the lifetimes of the radical ion-pairs of 100–170 ns. The electron transfer in the nanohybrids has further been utilized for light-to-electricity conversion by the construction of proof-of-concept photoelectrochemical solar cells." @default.
• W2125341423 created "2016-06-24" @default.
• W2125341423 creator A5024406805 @default.
• W2125341423 creator A5029103780 @default.
• W2125341423 creator A5040954425 @default.
• W2125341423 creator A5048163259 @default.
• W2125341423 creator A5055809552 @default.
• W2125341423 creator A5060584552 @default.
• W2125341423 creator A5062868414 @default.
• W2125341423 creator A5080787029 @default.
• W2125341423 date "2012-01-01" @default.
• W2125341423 modified "2023-10-18" @default.
• W2125341423 title "Photoinduced charge separation in three-layer supramolecular nanohybrids: fullerene–porphyrin–SWCNT" @default.
• W2125341423 cites W1497938811 @default.
• W2125341423 cites W1520363451 @default.
• W2125341423 cites W1530818404 @default.
• W2125341423 cites W1965763472 @default.
• W2125341423 cites W1974099782 @default.
• W2125341423 cites W1976870657 @default.
• W2125341423 cites W1978731356 @default.
• W2125341423 cites W1979198302 @default.
• W2125341423 cites W1979309477 @default.
• W2125341423 cites W1984674260 @default.
• W2125341423 cites W1989217436 @default.
• W2125341423 cites W1990787291 @default.
• W2125341423 cites W1999183479 @default.
• W2125341423 cites W2011344355 @default.
• W2125341423 cites W2012101865 @default.
• W2125341423 cites W2015467958 @default.
• W2125341423 cites W2034316305 @default.
• W2125341423 cites W2034910201 @default.
• W2125341423 cites W2042003304 @default.
• W2125341423 cites W2043836941 @default.
• W2125341423 cites W2050720181 @default.
• W2125341423 cites W2051240069 @default.
• W2125341423 cites W2054377197 @default.
• W2125341423 cites W2062846270 @default.
• W2125341423 cites W2065538727 @default.
• W2125341423 cites W2069506896 @default.
• W2125341423 cites W2072896100 @default.
• W2125341423 cites W2086222788 @default.
• W2125341423 cites W2086915866 @default.
• W2125341423 cites W2088308014 @default.
• W2125341423 cites W2089565107 @default.
• W2125341423 cites W2092053874 @default.
• W2125341423 cites W2094346859 @default.
• W2125341423 cites W2099469215 @default.
• W2125341423 cites W2100350057 @default.
• W2125341423 cites W2101184478 @default.
• W2125341423 cites W2117555577 @default.
• W2125341423 cites W2133956346 @default.
• W2125341423 cites W2134035658 @default.
• W2125341423 cites W2140911915 @default.
• W2125341423 cites W2147357490 @default.
• W2125341423 cites W2152286478 @default.
• W2125341423 cites W2152402731 @default.
• W2125341423 cites W2161638199 @default.
• W2125341423 cites W2163656669 @default.
• W2125341423 cites W2168382386 @default.
• W2125341423 cites W2314580452 @default.
• W2125341423 cites W2317555899 @default.
• W2125341423 cites W2333098409 @default.
• W2125341423 cites W2950168003 @default.
• W2125341423 cites W2950257340 @default.
• W2125341423 cites W2951227056 @default.
• W2125341423 cites W2952197875 @default.
• W2125341423 cites W4236735152 @default.
• W2125341423 cites W4249652017 @default.
• W2125341423 cites W4366807521 @default.
• W2125341423 doi "https://doi.org/10.1039/c2cp23643e" @default.
• W2125341423 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22262196" @default.
• W2125341423 hasPublicationYear "2012" @default.
• W2125341423 type Work @default.
• W2125341423 sameAs 2125341423 @default.
• W2125341423 citedByCount "17" @default.
• W2125341423 countsByYear W21253414232012 @default.
• W2125341423 countsByYear W21253414232013 @default.
• W2125341423 countsByYear W21253414232014 @default.
• W2125341423 countsByYear W21253414232015 @default.
• W2125341423 countsByYear W21253414232016 @default.
• W2125341423 countsByYear W21253414232019 @default.
• W2125341423 crossrefType "journal-article" @default.
• W2125341423 hasAuthorship W2125341423A5024406805 @default.
• W2125341423 hasAuthorship W2125341423A5029103780 @default.
• W2125341423 hasAuthorship W2125341423A5040954425 @default.
• W2125341423 hasAuthorship W2125341423A5048163259 @default.
• W2125341423 hasAuthorship W2125341423A5055809552 @default.
• W2125341423 hasAuthorship W2125341423A5060584552 @default.
• W2125341423 hasAuthorship W2125341423A5062868414 @default.
• W2125341423 hasAuthorship W2125341423A5080787029 @default.
• W2125341423 hasConcept C121332964 @default.
• W2125341423 hasConcept C161790260 @default.
• W2125341423 hasConcept C162862793 @default.
• W2125341423 hasConcept C178790620 @default.
• W2125341423 hasConcept C185592680 @default.
• W2125341423 hasConcept C26873012 @default.
• W2125341423 hasConcept C2779480358 @default.
• W2125341423 hasConcept C2779892579 @default.

• next