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- W2125598488 abstract "Methylazide reacts with alkenes bearing two electron-withdrawing substituents on the same sp2 carbone and leads to corresponding 1,2,3-triazolines with these substituents in 4 position. Thermolysis of these 1,2,3-triazolines give cycloreversion (alkene+methylazide) and aziridines after extrusion of nitrogen. In the conditions of the thermolysis, aziridine carbone-carbone bond breaks, leading to azomethine ylids that are trapped with alkenes and give pyrrolidines." @default.
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- W2125598488 date "2010-08-31" @default.
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- W2125598488 title "Addition du méthylazide aux oléfines portant une double substitution activante geminée. Étude de la stabilité thermique des triazol-1,2,3-ines obtenues" @default.
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- W2125598488 doi "https://doi.org/10.1002/bscb.19961050508" @default.
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