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- W2125816938 abstract "The products of the Br-atom initiated oxidation of trans-2-butene have been studied in a largevolume reaction chamber between 246 and 298 K using in situ FT-IR for the analysis. 3-Bromobutan-2-one, acetaldehyde and acetylbromide were the major products of this oxidation process. Additional products included formaldehyde and hydrogen bromide and evidence was found for the formation of 3-bromobutan-2-hydroperoxide. Decreasing the temperature from 298 K down to 246 K resulted in an increase in the yield of 3-bromobutan-2-one and a decrease in the yields of acetaldehyde, acetylbromide, formaldehyde and hydrogen bromide. Addition of NO to the reaction system resulted in nearly a doubling of the yields of 3-bromobutan-2-one, acetaldehyde and formaldehyde. The reaction mechanism is discussed and possible consequences of the results for the involvement of bromine/alkene chemistry in the springtime depletion of ozone in the Arctic are considered." @default.
- W2125816938 created "2016-06-24" @default.
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- W2125816938 date "1997-01-01" @default.
- W2125816938 modified "2023-10-17" @default.
- W2125816938 title "FT-IR product study of the gas-phase Br-initiated oxidation of trans-2-butene under atmospheric conditions between 246 and 298 K" @default.
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- W2125816938 doi "https://doi.org/10.3402/tellusb.v49i5.16009" @default.
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