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• W2125887127 abstract "BaSO 4 precipitation membranes generated in cellophane skins by interdiffusion of equal concentrated aqueous solutions of BaCl 2 and K 2 SO 4 exhibit a non-ohmic electric current characteristic. Measurements of electric current relaxation triggered by lumps of electric potential in foreward and backward bias direction are used to study the possibility to store and recall known small amounts of electric charge in form of mobile ions within the membrane phase. The results give support to the assumption that BaSO 4 precipitation membranes have a sandwich like structure composed of a layer of crystallites with cation exchange properties and a layer of crystallites with anion exchange properties. The transference number of the counter ions (t counter ) in these layers depends strongly on the concentration of electrolyte within the precipitation zone which can be increased by pulses of electric current of variable duration passing the membrane in foreward bias direction. t counter decreases with increasing with increasing electrolyte concentration within the precipitation zone. For the reason BaSO 4 precipitation membranes cannot be used to store electric charge (in form of mobile ions) without loss even for short periods of time" @default.
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• W2125887127 date "1989-12-01" @default.
• W2125887127 modified "2023-09-24" @default.
• W2125887127 title "Study of Electrochemical Properties of Inorganic Precipitation Membranes using Measurements of Electric Current Relaxation under Potentiostatic Conditions" @default.
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• W2125887127 doi "https://doi.org/10.1002/bbpc.19890931220" @default.
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