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• W2125896965 abstract "Square-wave (SW) voltammetry in connection with a hanging mercury drop electrode has been applied for studying the reduction of Ge(IV) catalyzed by o-catechol after adsorptive preconcentration. Acetate buffer solutions with low and high analytical concentrations of o-catechol [with respect to that of Ge(IV)] have been used. Dependences of SW catalytic peaks on accumulation conditions have been attributed to the formation of the catalytic complexes via a direct-adsorption mechanism. The nature of the electrocatalytic process (involving an apparently quasi-reversible electrode reaction with an adsorbed reactant and a diffusing product) allows us to explain complex dependences of catalytic peaks on SW-parameters. Adequate conditions for determination of o-catechol and Ge(IV) by means of SW catalytic adsorptive voltammetry have been established." @default.
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• W2125896965 date "2001-01-05" @default.
• W2125896965 modified "2023-09-26" @default.
• W2125896965 title "Square-wave voltammetry of the o-catechol–Ge(IV) catalytic system after adsorptive preconcentration at a hanging mercury drop electrode" @default.
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• W2125896965 doi "https://doi.org/10.1016/s0039-9140(00)00508-7" @default.
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