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• W2126115808 abstract "Abstract A novel main‐chain azobenzene cyclic polymer, cyclic‐ PEHPA, has been successfully synthesized by ‘click’ cyclization of the α ‐alkyne‐ ω ‐azido hetero‐difunctional linear precursors ( linear‐ PEHPA), which is synthesized by a step‐growth polymerization of the 3′‐ethynylphenyl[4‐hexyl‐(2‐azido‐2‐methyl‐ propionate) phenyl] azobenzene (EHPA). Gel permeation chromatography, and 1 H NMR and FT‐IR spectra confirmed the complete transformation of linear ‐PEHPA into cyclic‐ PEHPA. With the same molecular weights, the cyclic‐ PEHPAs are found to have higher glass transition temperatures than the linear‐ PEHPAs, but almost the same decomposition temperatures. In addition, the obtained cyclic azobenzene polymer with lower molar mass shows a slightly better trans–cis–trans photoisomerization ability than the corresponding linear‐ PEHPA. magnified image" @default.
• W2126115808 created "2016-06-24" @default.
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• W2126115808 date "2010-07-16" @default.
• W2126115808 modified "2023-10-18" @default.
• W2126115808 title "The First Example of Main-Chain Cyclic Azobenzene Polymers" @default.
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• W2126115808 doi "https://doi.org/10.1002/marc.201000218" @default.
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