Matches in SemOpenAlex for { <https://semopenalex.org/work/W2126157400> ?p ?o ?g. }
- W2126157400 endingPage "4246" @default.
- W2126157400 startingPage "4240" @default.
- W2126157400 abstract "We present here phase equilibria calculations of polyethylene solutions in different solvents as obtained with two versions of the SAFT equation of state, soft-SAFT and PC-SAFT. The objective of this work is twofold: to check the accuracy of the soft-SAFT equation in providing reliable polymer solutions behavior and to propose a methodology from which systematic studies on polymer solutions can be made by the use of transferable molecular parameters. Some issues regarding the fitting of molecular parameters from polymer data as well as the numerical problems associated with polymer phase equilibria calculations are also mentioned. The methodology is applied to model the phase equilibria of polyethylene solutions with several solvents, differing in size and polarity, including n-pentane, n-hexane, butyl acetate, and pentanol, and results are compared to available experimental data. The phase behavior explored in this work is wide, from vapor−liquid equilibria to liquid−liquid equilibria, displaying upper critical solution temperatures and lower critical solution temperatures. We have also calculated the solubility of ethylene in polyethylene with the same models. Results obtained from the soft-SAFT equation are slightly more accurate in some of the cases than the PC-SAFT equation. Both equations, soft-SAFT and PC-SAFT, follow most of the experimental trends, providing accurate predictions from pure component parameters in some of the cases, while a binary interaction parameter was needed for the butyl acetate, 1-pentanol, and ethylene binary mixtures." @default.
- W2126157400 created "2016-06-24" @default.
- W2126157400 creator A5024375429 @default.
- W2126157400 creator A5058646846 @default.
- W2126157400 creator A5080917877 @default.
- W2126157400 creator A5090541369 @default.
- W2126157400 date "2006-05-19" @default.
- W2126157400 modified "2023-09-26" @default.
- W2126157400 title "Phase Equilibria Calculations of Polyethylene Solutions from SAFT-Type Equations of State" @default.
- W2126157400 cites W1972839841 @default.
- W2126157400 cites W2008312376 @default.
- W2126157400 cites W2016503547 @default.
- W2126157400 cites W2019235610 @default.
- W2126157400 cites W2023684075 @default.
- W2126157400 cites W2034798832 @default.
- W2126157400 cites W2042921792 @default.
- W2126157400 cites W2045025542 @default.
- W2126157400 cites W2062770487 @default.
- W2126157400 cites W2062770958 @default.
- W2126157400 cites W2063477305 @default.
- W2126157400 cites W2078639426 @default.
- W2126157400 cites W2085237940 @default.
- W2126157400 cites W2087240271 @default.
- W2126157400 cites W2089176522 @default.
- W2126157400 cites W2100526712 @default.
- W2126157400 cites W2105898331 @default.
- W2126157400 cites W2132606431 @default.
- W2126157400 cites W2497590227 @default.
- W2126157400 doi "https://doi.org/10.1021/ma060584a" @default.
- W2126157400 hasPublicationYear "2006" @default.
- W2126157400 type Work @default.
- W2126157400 sameAs 2126157400 @default.
- W2126157400 citedByCount "39" @default.
- W2126157400 countsByYear W21261574002012 @default.
- W2126157400 countsByYear W21261574002013 @default.
- W2126157400 countsByYear W21261574002014 @default.
- W2126157400 countsByYear W21261574002015 @default.
- W2126157400 countsByYear W21261574002016 @default.
- W2126157400 countsByYear W21261574002017 @default.
- W2126157400 countsByYear W21261574002018 @default.
- W2126157400 countsByYear W21261574002019 @default.
- W2126157400 countsByYear W21261574002020 @default.
- W2126157400 countsByYear W21261574002021 @default.
- W2126157400 countsByYear W21261574002022 @default.
- W2126157400 countsByYear W21261574002023 @default.
- W2126157400 crossrefType "journal-article" @default.
- W2126157400 hasAuthorship W2126157400A5024375429 @default.
- W2126157400 hasAuthorship W2126157400A5058646846 @default.
- W2126157400 hasAuthorship W2126157400A5080917877 @default.
- W2126157400 hasAuthorship W2126157400A5090541369 @default.
- W2126157400 hasBestOaLocation W21261574002 @default.
- W2126157400 hasConcept C121332964 @default.
- W2126157400 hasConcept C147789679 @default.
- W2126157400 hasConcept C155574463 @default.
- W2126157400 hasConcept C178790620 @default.
- W2126157400 hasConcept C185592680 @default.
- W2126157400 hasConcept C18762648 @default.
- W2126157400 hasConcept C192562407 @default.
- W2126157400 hasConcept C2777077568 @default.
- W2126157400 hasConcept C2779751980 @default.
- W2126157400 hasConcept C33923547 @default.
- W2126157400 hasConcept C43617362 @default.
- W2126157400 hasConcept C44280652 @default.
- W2126157400 hasConcept C48372109 @default.
- W2126157400 hasConcept C521977710 @default.
- W2126157400 hasConcept C53810900 @default.
- W2126157400 hasConcept C94375191 @default.
- W2126157400 hasConcept C97355855 @default.
- W2126157400 hasConcept C98765843 @default.
- W2126157400 hasConceptScore W2126157400C121332964 @default.
- W2126157400 hasConceptScore W2126157400C147789679 @default.
- W2126157400 hasConceptScore W2126157400C155574463 @default.
- W2126157400 hasConceptScore W2126157400C178790620 @default.
- W2126157400 hasConceptScore W2126157400C185592680 @default.
- W2126157400 hasConceptScore W2126157400C18762648 @default.
- W2126157400 hasConceptScore W2126157400C192562407 @default.
- W2126157400 hasConceptScore W2126157400C2777077568 @default.
- W2126157400 hasConceptScore W2126157400C2779751980 @default.
- W2126157400 hasConceptScore W2126157400C33923547 @default.
- W2126157400 hasConceptScore W2126157400C43617362 @default.
- W2126157400 hasConceptScore W2126157400C44280652 @default.
- W2126157400 hasConceptScore W2126157400C48372109 @default.
- W2126157400 hasConceptScore W2126157400C521977710 @default.
- W2126157400 hasConceptScore W2126157400C53810900 @default.
- W2126157400 hasConceptScore W2126157400C94375191 @default.
- W2126157400 hasConceptScore W2126157400C97355855 @default.
- W2126157400 hasConceptScore W2126157400C98765843 @default.
- W2126157400 hasIssue "12" @default.
- W2126157400 hasLocation W21261574001 @default.
- W2126157400 hasLocation W21261574002 @default.
- W2126157400 hasOpenAccess W2126157400 @default.
- W2126157400 hasPrimaryLocation W21261574001 @default.
- W2126157400 hasRelatedWork W1993306281 @default.
- W2126157400 hasRelatedWork W2008221318 @default.
- W2126157400 hasRelatedWork W2016898163 @default.
- W2126157400 hasRelatedWork W2034468282 @default.
- W2126157400 hasRelatedWork W2044354934 @default.
- W2126157400 hasRelatedWork W2049819945 @default.