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• W2126264534 abstract "Tetranuclear carboxylate clusters with the general structural formula [M4(L)2(O2CR)4] (M = Cd, Zn; LH2 = 2,6-bis(1-(2-hydroxyphenyl)-iminoethyl)pyridine; R = CH3, C6H5) were studied by variable-temperature (VT) 1H NMR spectroscopy. The dynamics of these clusters in solution can be described by two uncorrelated dynamical processes. The first dynamical process is the interconversion, both inter- as well as intramolecular, between syn–syn bridging and chelating carboxylate ligands. It is shown that this carboxylate interconversion mechanism is predominantly intramolecular for [Cd4(L)2(O2CCH3)4] (1a), whereas for [Zn4(L)2(O2CCH3)4] (2a) it is predominantly intermolecular. Two models for the second dynamic process, which involves the diiminepyridine ligand, are described. The first model comprises a nondissociative rotation around an internal axis, which changes the chirality of the cluster. The second model is based on the dissociation of the tetranuclear cluster into two dimeric species, which recombine again. This last model is supported by scrambling experiments between [Zn4(L)2(O2CCH3)4] (2a) and [Zn4(L3)2(O2CCH3)4] (5) (L3H2 = 2,6-bis(1-(2-hydroxyphenyl)-iminoethyl)4-chloropyridine)." @default.
• W2126264534 created "2016-06-24" @default.
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• W2126264534 creator A5043545998 @default.
• W2126264534 creator A5047557529 @default.
• W2126264534 creator A5052072204 @default.
• W2126264534 date "2013-10-31" @default.
• W2126264534 modified "2023-09-25" @default.
• W2126264534 title "Uncorrelated Dynamical Processes in Tetranuclear Carboxylate Clusters Studied by Variable-Temperature ¹H NMR Spectroscopy." @default.
• W2126264534 cites W1582718027 @default.
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• W2126264534 cites W1966012381 @default.
• W2126264534 cites W1972444280 @default.
• W2126264534 cites W1975493568 @default.
• W2126264534 cites W1977917160 @default.
• W2126264534 cites W1978296916 @default.
• W2126264534 cites W1979103455 @default.
• W2126264534 cites W1981704948 @default.
• W2126264534 cites W1981748997 @default.
• W2126264534 cites W1985469967 @default.
• W2126264534 cites W1985847003 @default.
• W2126264534 cites W1986171863 @default.
• W2126264534 cites W1987727535 @default.
• W2126264534 cites W1987770897 @default.
• W2126264534 cites W1987946602 @default.
• W2126264534 cites W1988785503 @default.
• W2126264534 cites W1991883335 @default.
• W2126264534 cites W1995979682 @default.
• W2126264534 cites W1999096297 @default.
• W2126264534 cites W2000835462 @default.
• W2126264534 cites W2008201070 @default.
• W2126264534 cites W2009000124 @default.
• W2126264534 cites W2014168748 @default.
• W2126264534 cites W2015726498 @default.
• W2126264534 cites W2015946951 @default.
• W2126264534 cites W2018191624 @default.
• W2126264534 cites W2019950698 @default.
• W2126264534 cites W2021809350 @default.
• W2126264534 cites W2023065391 @default.
• W2126264534 cites W2025252058 @default.
• W2126264534 cites W2026407607 @default.
• W2126264534 cites W2032787413 @default.
• W2126264534 cites W2035227356 @default.
• W2126264534 cites W2036079515 @default.
• W2126264534 cites W2037059975 @default.
• W2126264534 cites W2037448564 @default.
• W2126264534 cites W2041114202 @default.
• W2126264534 cites W2044742408 @default.
• W2126264534 cites W2046143208 @default.
• W2126264534 cites W2050063778 @default.
• W2126264534 cites W2057833130 @default.
• W2126264534 cites W2057863409 @default.
• W2126264534 cites W2060531375 @default.
• W2126264534 cites W2061737978 @default.
• W2126264534 cites W2068323023 @default.
• W2126264534 cites W2070510137 @default.
• W2126264534 cites W2072166607 @default.
• W2126264534 cites W2073237479 @default.
• W2126264534 cites W2076388616 @default.
• W2126264534 cites W2077749836 @default.
• W2126264534 cites W2080488356 @default.
• W2126264534 cites W2080665513 @default.
• W2126264534 cites W2081362524 @default.
• W2126264534 cites W2082080415 @default.
• W2126264534 cites W2083907491 @default.
• W2126264534 cites W2087006788 @default.
• W2126264534 cites W2093974353 @default.
• W2126264534 cites W209433882 @default.
• W2126264534 cites W2098472363 @default.
• W2126264534 cites W2101950430 @default.
• W2126264534 cites W2107733783 @default.
• W2126264534 cites W2110341062 @default.
• W2126264534 cites W2112032031 @default.
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• W2126264534 cites W2145144268 @default.
• W2126264534 cites W2164932081 @default.
• W2126264534 cites W2172127362 @default.
• W2126264534 cites W2276961241 @default.
• W2126264534 cites W2312813608 @default.
• W2126264534 cites W2313252074 @default.
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• W2126264534 doi "https://doi.org/10.1021/ic401522v" @default.
• W2126264534 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24175921" @default.
• W2126264534 hasPublicationYear "2013" @default.
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