FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2126427098> ?p ?o ?g. }

• W2126427098 endingPage "9440" @default.
• W2126427098 startingPage "9433" @default.
• W2126427098 abstract "A simple and high-yielding method for the preparation of cyclopropane amino acids is described. The novel method involves the one-pot cyclopropanation of readily available dehydroamino acids using aryl and unsaturated diazo compounds generated in situ from the corresponding tosylhydrazone salts. It was found that thermal 1,3-dipolar cycloaddition followed by nitrogen extrusion gave the cyclopropane amino acid derivatives with good E selectivity, while reactions in the presence of meso-tetraphenylporphyrin iron chloride gave predominantly the corresponding Z isomers. The synthetic utility of this process was demonstrated in the synthesis of (+/-)-(Z)-2,3-methanophenylalanine [(+/-)-(Z)-1], the anti-Parkinson (+/-)-(E)-2,3-methano-m-tyrosine [(+/-)-(E)-2], and the natural product (+/-)-coronamic acid [(+/-)-3]." @default.
• W2126427098 created "2016-06-24" @default.
• W2126427098 creator A5032632797 @default.
• W2126427098 creator A5049280847 @default.
• W2126427098 creator A5053198446 @default.
• W2126427098 creator A5063975231 @default.
• W2126427098 creator A5064022391 @default.
• W2126427098 creator A5065371371 @default.
• W2126427098 creator A5066491744 @default.
• W2126427098 creator A5066800714 @default.
• W2126427098 creator A5070273788 @default.
• W2126427098 creator A5078544922 @default.
• W2126427098 date "2003-11-01" @default.
• W2126427098 modified "2023-10-12" @default.
• W2126427098 title "Diastereoselective Synthesis of Cyclopropane Amino Acids Using Diazo Compounds Generated in Situ" @default.
• W2126427098 cites W1973359123 @default.
• W2126427098 cites W1977571871 @default.
• W2126427098 cites W1978058536 @default.
• W2126427098 cites W1997208794 @default.
• W2126427098 cites W2004717010 @default.
• W2126427098 cites W2028831685 @default.
• W2126427098 cites W2036845887 @default.
• W2126427098 cites W2044416346 @default.
• W2126427098 cites W2057717450 @default.
• W2126427098 cites W2060646523 @default.
• W2126427098 cites W2062161688 @default.
• W2126427098 cites W2069218765 @default.
• W2126427098 cites W2075390301 @default.
• W2126427098 cites W2088128361 @default.
• W2126427098 cites W2095073558 @default.
• W2126427098 cites W334918 @default.
• W2126427098 cites W4211052293 @default.
• W2126427098 doi "https://doi.org/10.1021/jo035060c" @default.
• W2126427098 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14629169" @default.
• W2126427098 hasPublicationYear "2003" @default.
• W2126427098 type Work @default.
• W2126427098 sameAs 2126427098 @default.
• W2126427098 citedByCount "83" @default.
• W2126427098 countsByYear W21264270982012 @default.
• W2126427098 countsByYear W21264270982013 @default.
• W2126427098 countsByYear W21264270982014 @default.
• W2126427098 countsByYear W21264270982015 @default.
• W2126427098 countsByYear W21264270982016 @default.
• W2126427098 countsByYear W21264270982017 @default.
• W2126427098 countsByYear W21264270982018 @default.
• W2126427098 countsByYear W21264270982019 @default.
• W2126427098 countsByYear W21264270982020 @default.
• W2126427098 countsByYear W21264270982021 @default.
• W2126427098 countsByYear W21264270982022 @default.
• W2126427098 countsByYear W21264270982023 @default.
• W2126427098 crossrefType "journal-article" @default.
• W2126427098 hasAuthorship W2126427098A5032632797 @default.
• W2126427098 hasAuthorship W2126427098A5049280847 @default.
• W2126427098 hasAuthorship W2126427098A5053198446 @default.
• W2126427098 hasAuthorship W2126427098A5063975231 @default.
• W2126427098 hasAuthorship W2126427098A5064022391 @default.
• W2126427098 hasAuthorship W2126427098A5065371371 @default.
• W2126427098 hasAuthorship W2126427098A5066491744 @default.
• W2126427098 hasAuthorship W2126427098A5066800714 @default.
• W2126427098 hasAuthorship W2126427098A5070273788 @default.
• W2126427098 hasAuthorship W2126427098A5078544922 @default.
• W2126427098 hasConcept C114373084 @default.
• W2126427098 hasConcept C155647269 @default.
• W2126427098 hasConcept C161790260 @default.
• W2126427098 hasConcept C178790620 @default.
• W2126427098 hasConcept C185592680 @default.
• W2126427098 hasConcept C202751555 @default.
• W2126427098 hasConcept C2776904781 @default.
• W2126427098 hasConcept C2777052750 @default.
• W2126427098 hasConcept C2779200411 @default.
• W2126427098 hasConcept C2779664164 @default.
• W2126427098 hasConcept C2780378348 @default.
• W2126427098 hasConcept C515207424 @default.
• W2126427098 hasConcept C55493867 @default.
• W2126427098 hasConcept C71240020 @default.
• W2126427098 hasConceptScore W2126427098C114373084 @default.
• W2126427098 hasConceptScore W2126427098C155647269 @default.
• W2126427098 hasConceptScore W2126427098C161790260 @default.
• W2126427098 hasConceptScore W2126427098C178790620 @default.
• W2126427098 hasConceptScore W2126427098C185592680 @default.
• W2126427098 hasConceptScore W2126427098C202751555 @default.
• W2126427098 hasConceptScore W2126427098C2776904781 @default.
• W2126427098 hasConceptScore W2126427098C2777052750 @default.
• W2126427098 hasConceptScore W2126427098C2779200411 @default.
• W2126427098 hasConceptScore W2126427098C2779664164 @default.
• W2126427098 hasConceptScore W2126427098C2780378348 @default.
• W2126427098 hasConceptScore W2126427098C515207424 @default.
• W2126427098 hasConceptScore W2126427098C55493867 @default.
• W2126427098 hasConceptScore W2126427098C71240020 @default.
• W2126427098 hasIssue "24" @default.
• W2126427098 hasLocation W21264270981 @default.
• W2126427098 hasLocation W21264270982 @default.
• W2126427098 hasOpenAccess W2126427098 @default.
• W2126427098 hasPrimaryLocation W21264270981 @default.
• W2126427098 hasRelatedWork W2037181430 @default.
• W2126427098 hasRelatedWork W2045420437 @default.
• W2126427098 hasRelatedWork W2344238170 @default.
• W2126427098 hasRelatedWork W2510809889 @default.

• next