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• W2126448799 abstract "Pyrene derivatives can be incorporated into nucleic acid analogs in order to obtain switchable probes or supramolecular architectures. In this paper, peptide nucleic acids (PNAs) containing 1 to 3 1-pyreneacetic acid units ( PNA1 – 6 ) with a sequence with prevalence of pyrimidine bases, complementary to cystic fibrosis W1282X point mutation were synthesized. These compounds showed sequence-selective switch-on of pyrene excimer emission in the presence of target DNA, due to PNA 2 DNA triplex formation, with stability depending on the number and positioning of the pyrene units along the chain. An increase in triplex stability and a very high mismatch-selectivity, derived from combined stacking and base-pairing interactions, were found for PNA2 , bearing two distant pyrene units." @default.
• W2126448799 created "2016-06-24" @default.
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• W2126448799 date "2014-07-02" @default.
• W2126448799 modified "2023-09-25" @default.
• W2126448799 title "Pyrene-modified PNAs: Stacking interactions and selective excimer emission in PNA₂DNA triplexes" @default.
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• W2126448799 doi "https://doi.org/10.3762/bjoc.10.154" @default.
• W2126448799 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4142857" @default.
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