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• W2126530836 abstract "Nanoclusters AgI have been prepared in the channels of SBA-15 molecular sieve host, and the host-guest nanocomposite materials were prepared by a heat diffusion method. The (SBA-15)-AgI host-guest nanocomposites were characterized by powder X-ray diffraction analysis, nitrogen adsorption-desorption isotherms at 77 K, and solid-state diffuse reflectance absorption spectra. The decrease in surface area, pore diameter, and pore volume showed the existence of silver iodide clusters in the channels of SBA-15 host. X-ray diffraction illustrates that the framework of the SBA-15 remained in the host-guest composites of (SBA-15)-AgI. As the guest loading decreases, a blue-shift was observed in the diffuse reflectance spectra. This shows that the guest existed in the channels of SBA-15 and a quantum confinement effect emerged. The photoluminescence (PL) spectra show that the PL at ∼2.38 eV, associated with the hydrogen-related species, decreases substantially after the loading of AgI in SBA-15. The decrease of the PL indicates the reduction of the hydrogen concentration on the pore surface of SBA-15 after the loading of AgI guest. The intensity decrease of the self-trapped exciton (STE) band at 2.76 eV also suggests a hindrance for generating the excitons upon adding the AgI guest into the SBA-15 host." @default.
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• W2126530836 date "2003-02-01" @default.
• W2126530836 modified "2023-09-27" @default.
• W2126530836 title "Optical Properties of Host(SBA-15)-guest(AgI) Composite Materials" @default.
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• W2126530836 doi "https://doi.org/10.1002/jccs.200300008" @default.
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