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- W2126642315 abstract "Entirely different product distributions were observed when the bisdiazo compound 1 was irradiated by a conventional lamp (254 nm) on the one hand and by a pulsed excimer laser (248 nm) on the other. Continuous photolysis gave a complex reaction mixture (Scheme 2), of which eight products were identified. Pulsed laser photolysis gave (11E)-dibenzocyclooctatriene 20 as a new product in 49% yield (Scheme 4). We postulate that compound 20 is formed via the biscarbene intermediate 18 which results from the sequential absorption of two photons by a single molecule within a single laser pulse." @default.
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- W2126642315 date "1988-12-14" @default.
- W2126642315 modified "2023-09-26" @default.
- W2126642315 title "Conventional and Laser Photolysis of a Bisdiazo Compound" @default.
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- W2126642315 doi "https://doi.org/10.1002/hlca.19880710802" @default.
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