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• W2126655881 endingPage "12913" @default.
• W2126655881 startingPage "12908" @default.
• W2126655881 abstract "Abstract Cyclic amines such as pyrrolidine undergo redox‐annulations with 2‐formylaryl malonates. Concurrent oxidative amine α‐CH bond functionalization and reductive N‐alkylation render this transformation redox‐neutral. This redox‐Mannich process provides regioisomers of classic Reinhoudt reaction products as an entry to the tetrahydroprotoberberine core, enabling the synthesis of (±)‐thalictricavine and its epimer. An unusually mild amine‐promoted dealkoxycarbonylation was discovered in the course of these studies." @default.
• W2126655881 created "2016-06-24" @default.
• W2126655881 creator A5033182199 @default.
• W2126655881 creator A5086008854 @default.
• W2126655881 date "2015-07-28" @default.
• W2126655881 modified "2023-10-18" @default.
• W2126655881 title "Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core" @default.
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