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• W2126678423 abstract "gem-Dibromocyclopropane 1, prepared from tri-O-benzyl-D-glucal, undergoes thermal and silver-promoted ring expansion in the presence of alcohols to give substituted oxepines. With further heating, ring contraction to highly substituted tetrahydrofurans follows. These represent C-furanosides, potentially useful as precursors to C-nucleosides and other carbohydrate mimics." @default.
• W2126678423 created "2016-06-24" @default.
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• W2126678423 date "2011-01-01" @default.
• W2126678423 modified "2023-10-17" @default.
• W2126678423 title "Synthesis of C-furanosides from a<scp>d</scp>-glucal-derived cyclopropane through a ring-expansion/ring-contraction sequence" @default.
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• W2126678423 doi "https://doi.org/10.1039/c0cc02244f" @default.
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