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• W2127029754 abstract "Abstract BACKGROUND Enantiopure epoxides and diols have attracted much attention as important building blocks for the production of flavorings, agrochemicals and pharmaceutical products. Enantioselective hydrolysis reaction of rac ‐epoxide in a biphasic system using whole cell catalysts is one of the promising methods to obtain enantiopure compounds . RESULTS The kinetic resolution of racemic 1,2‐epoxyhexane was carried out using whole cell biocatalyst in a hydrophobic solvent/buffer biphasic system and the effect of organic solvents and ionic liquids on the initial reaction rate of ( R )‐enantiomer, r R0 and enantiomeric ratio, E was examined. In the case of using hydrophobic hydrocarbons, r R0 increased with the hydrophobicity of hydrocarbon (log P O/W ), and a linear correlation was observed between r R0 and log P O/W . On the other hand, there were no correlations between r R0 and log P O/W of ionic liquids. Moreover, effects on E were small in both solvents. However, the addition of 1‐heptanol to dodecane was very effective at increasing E value. The kinetic data correlated well with the reaction kinetic model, considering the distribution between two liquid phases and competitive product inhibition . CONCLUSION The high enantiomeric ratio of ( R )‐diol ( E >100) without significant decrease in the reactivity was accomplished by adding 1‐heptanol in minute amounts to dodecane. © 2013 Society of Chemical Industry" @default.
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• W2127029754 date "2013-07-04" @default.
• W2127029754 modified "2023-10-07" @default.
• W2127029754 title "Effect of organic solvents and ionic liquids on resolution of 2‐epoxyhexane by whole cells of <i>Rhodotorula glutinis</i> in a two‐liquid phase system" @default.
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• W2127029754 doi "https://doi.org/10.1002/jctb.4148" @default.
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