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- W2127082575 abstract "Hydrogen abstraction from boron trimethyl has been studied using the abstracting radicals CF3 and CD3, from the photolysis of the corresponding ketones over the temperature range of 150° to 300°C. The following Arrhenius parameters were obtained: The difference E – E in the case of BMe3 is considered due, in part, to polar effects. An exchange reaction is proposed for both CF3 and CD3 in collisions with BMe3: Radical combination of CF3 and CH2BMe2 leads to a hot molecule which undergoes a β-fluoro rearrangement elimination process, or a stabilized molecule which can thermally decompose:" @default.
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- W2127082575 date "1971-07-01" @default.
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- W2127082575 title "The reactions of CF3 and CD3 radicals with boron trimethyl" @default.
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- W2127082575 doi "https://doi.org/10.1002/kin.550030403" @default.
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