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- W2127164964 abstract "A model for calculation of the pressure tensor components is developed on the basis of some general results in the thermodynamics and statistical mechanics of spherical interfaces. The van der Waals intermolecular forces are taken into consideration. The model contains three parameters which are to be found from experiments. These are the interfacial tension of a flat interface and the Hamaker constants of the two neighboring phases. Then the model allows calculation of the interfacial bending moment, of the Tolman length and of the curvature dependence of the interfacial tension. Numerical results are obtained for various liquid-gas and water-oil interfaces at different radii of curvature. The results agree well with statistical-mechanical calculations and computer simulations by other authors. The calculated mechanical and thermodynamical interfacial tensions turn out to differ appreciably for drop radii below 1000 Å owing to the bending moment effect. The results can be applied for calculation of the size distribution and other properties of different fluid dispersions, including microemulsions." @default.
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- W2127164964 date "1991-01-01" @default.
- W2127164964 modified "2023-10-16" @default.
- W2127164964 title "The van der Waals component of interfacial bending moment 2. Model development and numerical results" @default.
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- W2127164964 doi "https://doi.org/10.1016/0166-6622(91)80117-7" @default.
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