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- W2127195763 abstract "A highly efficient enantioselective addition of Me2Zn to α-ketoesters, assisted by a chiral perhydro-1,3-benzoxazine ligand, is described. This novel catalytic system offers homogeneous elevated enantioselectivities in the preparation of α-hydroxyesters that bear a quaternary stereocenter, with a minor dependence on electronic and steric effects when aromatic, heteroaromatic, or aliphatic α-ketoesters are employed. The catalyst can be recovered and reused without loss of activity." @default.
- W2127195763 created "2016-06-24" @default.
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- W2127195763 date "2012-02-23" @default.
- W2127195763 modified "2023-10-03" @default.
- W2127195763 title "Highly Homogeneous Stereocontrolled Construction of Quaternary Hydroxyesters by Addition of Dimethylzinc to α-Ketoesters Promoted by Chiral Perhydrobenzoxazines and B(OEt)3" @default.
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- W2127195763 doi "https://doi.org/10.1002/chem.201102913" @default.
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