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- W2127237210 abstract "The two new cluster compounds, Cs4Re6S8(N3)6·H2O (1) and Na2Mo6Br8(N3)6·2H2O (2), have been prepared via solution chemistry route, starting from the Cs4Re6S8Br6CsBr and Mo6Br12 precursors synthesized by solid state chemistry techniques, and structurally characterized (crystal data: Cs4Re6S8(N3)6·H2O (1): Orthorhombic, space group Pnam, a=10.0651(1) Å, b=15.8856(2) Å, c=20.1714(3) Å, V=3225.2(7) Å3, Z=4, dcalc=4.48 g cm−3, μ=27.43 mm−1; Na2Mo6Br8(N3)6·2H2O (2): Orthorhombic, space group Ibam, a=11.5643(3) Å, b=14.3959(5) Å, c=17.0340(7) Å, V=2835.8(2) Å3, Z=4, dcalc=3.63 g cm−3, μ=13.91 mm−1). Their structures revealed that in both cases, the M6Li8 cluster core remains unchanged in the starting and final compounds whereas the bromine apical ligands (Bra) are substituted by N3 azide groups leading to M6Li8(N3)a6 cluster unit. The new Cs4Re6S8(N3)6·H2O is the first example of a compound containing an octahedral rhenium cluster coordinated to azide groups." @default.
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- W2127237210 date "2003-09-01" @default.
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- W2127237210 title "Syntheses and structures of two new M6Li8(N3)a6 cluster-unit based compounds: Cs4Re6S8(N3)6·H2O and Na2Mo6Br8(N3)6·2H2O" @default.
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- W2127237210 doi "https://doi.org/10.1016/s1293-2558(03)00143-2" @default.
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