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- W2127290767 abstract "The title compound (aplyroseol-14), C22H34O4, exhibits a lactone-based structure that is novel for spongian-type diterpenoids. The structure, which features a six-membered lactone ring, was proposed by Arnó, González & Zaragozá [J. Org. Chem. (2003), 68, 1242–1251] on the basis of spectroscopic data and chemical correlations. This assignment has been confirmed, and it is shown that the molecule contains a trans–anti–trans 6/6/6 tricyclic hydrocarbon system and that the acetoxymethyl group lies in an equatorial position. Pairs of near-linear C—H⋯O interactions link molecules into extended chains." @default.
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- W2127290767 date "2006-03-18" @default.
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- W2127290767 title "(–)-(5<i>S</i>,8<i>S</i>,9<i>R</i>,10<i>S</i>,13<i>R</i>,14<i>R</i>)-15,16-Dideoxy-16,17-epoxy-16-oxospongian-15-yl acetate" @default.
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- W2127290767 doi "https://doi.org/10.1107/s0108270106006366" @default.
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