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- W2127337732 abstract "Formal [2 + 2 + 2] addition reactions of [Cp*Ru(H2O)(NBD)]BF4 (NBD = norbornadiene) with PhCCR (R = H, COOEt) give [Cp*Ru(η6-C6H5C9H8R)] BF4 (1a, R = H; 2a, R = COOEt). Treatment of [Cp*Ru(H2O)(NBD)]BF4 with PhCCCCPh does not give [2 + 2 + 2] addition product, but [Cp*Ru(η6-C6H5CCCCPh)] BF4(3a). Treatment of 1a, 2a, 3a with NaBPh4 affords [Cp*Ru(η6-C6H5C9H8R)] BPh4 (1b, R = H; 2b, R = COOEt) and [Cp*Ru(η6-C6H5CCCCPh)] BPh4(3b). The structures of 1b, 2b and 3b were determined by X-ray crystallography. Copyright © 2007 John Wiley & Sons, Ltd." @default.
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- W2127337732 date "2007-01-01" @default.
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- W2127337732 title "Reactions of [Cp*Ru(H2O)(NBD)]+ with alkynes" @default.
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- W2127337732 doi "https://doi.org/10.1002/aoc.1288" @default.
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