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- W2127405428 endingPage "3474" @default.
- W2127405428 startingPage "3474" @default.
- W2127405428 abstract "We have established a unique Pd-catalyzed tetraallylation of C60 with allyl chloride and allylstannane that likely proceeds by the action of amphiphilic bis(π-allyl)palladium. Mechanistic analysis has revealed that both steric (for the first diallylation) and electronic (for the second diallylation) factors are responsible for high regioselectivity. The ring-closing metathesis reaction and hydrogenation of the tetraallylated product took place in the presence of Ru and Rh catalysts. Moreover, we found that chiral phosphoramidites are effective chiral ligands for the enantioselective tetraallylation of C60. Pronounced enantioselectivity up to 88% ee was realized in the production of tetraallylated C60." @default.
- W2127405428 created "2016-06-24" @default.
- W2127405428 creator A5003542044 @default.
- W2127405428 creator A5071016211 @default.
- W2127405428 creator A5081568695 @default.
- W2127405428 date "2012-01-01" @default.
- W2127405428 modified "2023-10-18" @default.
- W2127405428 title "Palladium-catalyzed tetraallylation of C60 with allyl chloride and allylstannane: mechanism, regioselectivity, and enantioselectivity" @default.
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