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• W2127419589 abstract "The kinetics of oxidative decolorization of acid orange 8 (AO8) by chloramine-T and bromamine-T in HClO4 medium has been investigated spectrophotometrically (λmax = 490 nm) at 298 K. Kinetic runs were executed under pretend first-order conditions of (oxidant)o >> (AO8)o. Under identical experimental conditions, reactions with both the oxidants follow identical kinetics with a first-order dependence on each (oxidant)o and (AO8) and a fractional-order dependence on (HClO4). Stoichiometry of the reaction was found to be 1:1 and the oxidation products were identified. The reaction was studied at dissimilar temperatures and activation parameters have been computed. Effects of p-toluenesulfonamide, halide ions, ionic strength and dielectric constant of the medium have been investigated. Reaction mixture fails to induce polymerization of acrylonitrile. The rate of oxidation of AO8 is about two-fold faster with BAT as compared to CAT. This may be endorsed to the diversity in electrophilicities of Cl + and Br + ions and also the van der Waal's radii of chlorine" @default.
• W2127419589 created "2016-06-24" @default.
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• W2127419589 date "2014-01-01" @default.
• W2127419589 modified "2023-09-28" @default.
• W2127419589 title "Kinetics and mechanism of oxidative decolorization of azo dye acid orange 8 by sodium N-halo-p-tolenesulfonamides in acid medium: spectrophotometric approach" @default.
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• W2127419589 doi "https://doi.org/10.9790/5736-07734049" @default.
• W2127419589 hasPublicationYear "2014" @default.
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