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- W2127434554 abstract "Abstract The reactions of SO2 with halocarbonyl anions of rhodium and iridium, [M(CO)2X2]-(M=Rh, Ir; X=Cl, Br, I), were studied. Addition of neutral ligands, Ph3E (E = P, As, Sb) or pyridine, to the SO2 treated halo carbonyl solution resulted in the formation of various complexes according to the nature of the precursor complex and the ligand. The obtained complexes are formulated as Rh(CO)(SO2)(Ph3As)2Cl, [Rh(py)2(SO2)Cl].2H2O, Rh(CO)(SO2XPh3P)2Br, Rh2(CO)2(SO2)(Ph3Sb)2Br2, Rh(py)2(SO2)2I(C2H5OH), Rh(SO2)3I(C2H5OH) and Rh2(CO)2(SO2)3(Ph3Sb)2I2, Ir(SO2)2Br(H2O)2, [Ir(SO2)4(Ph3Sb)Br].6H2O, Ir(SO2)I(H2+O)2 and [Ir(SO2)2(Ph3As)I3].4H2O. All complexes obtained have been characterized by physicochemical methods." @default.
- W2127434554 created "2016-06-24" @default.
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- W2127434554 date "1995-07-01" @default.
- W2127434554 modified "2023-09-25" @default.
- W2127434554 title "Reaction of Sulfur Dioxide with Halocarbonyls of Rhodium and Iridium" @default.
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- W2127434554 doi "https://doi.org/10.1080/15533179508218275" @default.
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