Matches in SemOpenAlex for { <https://semopenalex.org/work/W2127452938> ?p ?o ?g. }
- W2127452938 endingPage "14099" @default.
- W2127452938 startingPage "14094" @default.
- W2127452938 abstract "Two solid solutions, La4Cu(3-x)Zn(x)MoO12 (0.05 < or = x < or = 0.20, SS1) and La4Cu(3-x)Zn(x)MoO12 (0.30 < or = x < or = 2.40, SS2), were synthesized at ambient pressure and at temperatures from 1025 to 1200 degrees C by traditional solid-state reactions. Their structures were determined from X-ray powder diffraction with the help of electron and neutron diffraction. The atomic arrangements of SS1 and SS2 are similar, but their space groups are different, Pmnm for SS1 and P-1 for SS2, respectively. The copper, zinc, and molybdenum are coordinated by oxygen in corner-sharing trigonal bipyramids that are sandwiched between layers of lanthanum cations. In the transition metal cations layer of SS2, the copper and zinc cations order into a Kagomé-like lattice of triangular clusters. The magnetism has been measured from 2 to 300 K and is highly influenced by the geometric arrangement of the Cu(II) and Zn(II) cations. The number of free electrons per three Cu atoms is close to one for all samples in SS1 and SS2 indicating that the system can be well expressed by independent Cu(II)3 clusters. Spontaneous magnetization was observed in the system." @default.
- W2127452938 created "2016-06-24" @default.
- W2127452938 creator A5000067107 @default.
- W2127452938 creator A5016375951 @default.
- W2127452938 creator A5019678862 @default.
- W2127452938 creator A5020667648 @default.
- W2127452938 creator A5036509456 @default.
- W2127452938 creator A5038689957 @default.
- W2127452938 creator A5039850713 @default.
- W2127452938 creator A5044387916 @default.
- W2127452938 creator A5049829974 @default.
- W2127452938 creator A5056514750 @default.
- W2127452938 creator A5060164974 @default.
- W2127452938 creator A5072403367 @default.
- W2127452938 creator A5085992125 @default.
- W2127452938 date "2005-09-17" @default.
- W2127452938 modified "2023-10-16" @default.
- W2127452938 title "La<sub>4</sub>Cu<sub>3-</sub><i><sub>x</sub></i>Zn<i><sub>x</sub></i>MoO<sub>12</sub>: Zinc-Doped Cuprates with Kagomé Lattices" @default.
- W2127452938 cites W1565495982 @default.
- W2127452938 cites W1592936133 @default.
- W2127452938 cites W1980638591 @default.
- W2127452938 cites W1982680708 @default.
- W2127452938 cites W1987438104 @default.
- W2127452938 cites W1987904051 @default.
- W2127452938 cites W2000449275 @default.
- W2127452938 cites W2016260972 @default.
- W2127452938 cites W2024511231 @default.
- W2127452938 cites W2031975877 @default.
- W2127452938 cites W2036773692 @default.
- W2127452938 cites W2055891591 @default.
- W2127452938 cites W2070782312 @default.
- W2127452938 cites W2071057714 @default.
- W2127452938 cites W2101653753 @default.
- W2127452938 cites W2128117725 @default.
- W2127452938 cites W2950866640 @default.
- W2127452938 cites W3212355991 @default.
- W2127452938 doi "https://doi.org/10.1021/ja053489a" @default.
- W2127452938 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16201832" @default.
- W2127452938 hasPublicationYear "2005" @default.
- W2127452938 type Work @default.
- W2127452938 sameAs 2127452938 @default.
- W2127452938 citedByCount "9" @default.
- W2127452938 countsByYear W21274529382012 @default.
- W2127452938 countsByYear W21274529382013 @default.
- W2127452938 countsByYear W21274529382014 @default.
- W2127452938 countsByYear W21274529382017 @default.
- W2127452938 countsByYear W21274529382020 @default.
- W2127452938 crossrefType "journal-article" @default.
- W2127452938 hasAuthorship W2127452938A5000067107 @default.
- W2127452938 hasAuthorship W2127452938A5016375951 @default.
- W2127452938 hasAuthorship W2127452938A5019678862 @default.
- W2127452938 hasAuthorship W2127452938A5020667648 @default.
- W2127452938 hasAuthorship W2127452938A5036509456 @default.
- W2127452938 hasAuthorship W2127452938A5038689957 @default.
- W2127452938 hasAuthorship W2127452938A5039850713 @default.
- W2127452938 hasAuthorship W2127452938A5044387916 @default.
- W2127452938 hasAuthorship W2127452938A5049829974 @default.
- W2127452938 hasAuthorship W2127452938A5056514750 @default.
- W2127452938 hasAuthorship W2127452938A5060164974 @default.
- W2127452938 hasAuthorship W2127452938A5072403367 @default.
- W2127452938 hasAuthorship W2127452938A5085992125 @default.
- W2127452938 hasConcept C106773901 @default.
- W2127452938 hasConcept C115624301 @default.
- W2127452938 hasConcept C120665830 @default.
- W2127452938 hasConcept C121332964 @default.
- W2127452938 hasConcept C130893637 @default.
- W2127452938 hasConcept C161790260 @default.
- W2127452938 hasConcept C176932811 @default.
- W2127452938 hasConcept C178790620 @default.
- W2127452938 hasConcept C179104552 @default.
- W2127452938 hasConcept C185592680 @default.
- W2127452938 hasConcept C197162081 @default.
- W2127452938 hasConcept C207114421 @default.
- W2127452938 hasConcept C26873012 @default.
- W2127452938 hasConcept C50515024 @default.
- W2127452938 hasConcept C535196362 @default.
- W2127452938 hasConcept C544778455 @default.
- W2127452938 hasConcept C549387045 @default.
- W2127452938 hasConcept C55493867 @default.
- W2127452938 hasConcept C555894677 @default.
- W2127452938 hasConcept C57863236 @default.
- W2127452938 hasConcept C73585123 @default.
- W2127452938 hasConcept C8010536 @default.
- W2127452938 hasConceptScore W2127452938C106773901 @default.
- W2127452938 hasConceptScore W2127452938C115624301 @default.
- W2127452938 hasConceptScore W2127452938C120665830 @default.
- W2127452938 hasConceptScore W2127452938C121332964 @default.
- W2127452938 hasConceptScore W2127452938C130893637 @default.
- W2127452938 hasConceptScore W2127452938C161790260 @default.
- W2127452938 hasConceptScore W2127452938C176932811 @default.
- W2127452938 hasConceptScore W2127452938C178790620 @default.
- W2127452938 hasConceptScore W2127452938C179104552 @default.
- W2127452938 hasConceptScore W2127452938C185592680 @default.
- W2127452938 hasConceptScore W2127452938C197162081 @default.
- W2127452938 hasConceptScore W2127452938C207114421 @default.
- W2127452938 hasConceptScore W2127452938C26873012 @default.
- W2127452938 hasConceptScore W2127452938C50515024 @default.
- W2127452938 hasConceptScore W2127452938C535196362 @default.