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- W2127486852 abstract "Abstract Evidence of two-phonon structures is reported for some intra-configurational crystal field transitions in layered V- and Cr-halides. In particular, the crystal field spectrum of CrBr 2 (3d 4 ) has been shown for the first time, since the exciton–phonon interaction, despite its unfilled e g orbitals, vanishes to first order yielding a two-phonon sequence in the 3 A l (G)+ 3 A 2 (F) band. It is suggested that the main mechanism for the occurrence of two-phonon progressions consists in the direct coupling of the incident photon to a two-phonon state via the second-order dipole moment operator." @default.
- W2127486852 created "2016-06-24" @default.
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- W2127486852 date "2000-12-01" @default.
- W2127486852 modified "2023-09-27" @default.
- W2127486852 title "Excitonic two-phonon progressions in transition metal compounds" @default.
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- W2127486852 doi "https://doi.org/10.1016/s0375-9601(00)00682-4" @default.
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