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- W2127500147 abstract "Mercury thioarsenate glasses (HgS)<sub>x</sub>(As<sub>2</sub>S<sub>3</sub>)<sub>1−x</sub>, 0.0 ≤<italic>x</italic>≤ 0.5, form a hybrid (HgS<sub>2/2</sub>)<sub>n</sub>chain/AsS<sub>3/2</sub>pyramidal network, highly unusual for metal chalcogenide glasses. This network is evidenced by Raman spectroscopy and DFT modelling and consistent with thermal properties. Nevertheless we cannot exclude completely the presence of a small fraction of HgS<sub>4/4</sub>tetrahedral units." @default.
- W2127500147 created "2016-06-24" @default.
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- W2127500147 date "2014-01-01" @default.
- W2127500147 modified "2023-10-16" @default.
- W2127500147 title "Mercury thioarsenate glasses: a hybrid chain/pyramidal network" @default.
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- W2127500147 doi "https://doi.org/10.1039/c4ra07811j" @default.
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