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- W2127524135 abstract "0 are ambient bulk modulus and its pressure derivative, respectively. The Hugoniots (shock equations of state) for stishovite, coesite and quartz achieve widely differing internal energy states at equal volume and therefore allow us to determine the Gruneisen parameter of stishovite. On the basis of the resulting P–V–Tequation of state for stishovite and previous studies on other phases on the MgO-SiO2 binary, the breakdown reaction of MgSiO3-perovskite to MgO and SiO2 was calculated. Our calculations show that perovskite is thermodynamically stable relative to the stishovite and periclase assemblage at lower mantle conditions. We obtain similar results for a range of models, despite the appreciable differences among these experimentbased thermodynamic parameters. INDEX TERMS: 3944 Mineral Physics: Shock wave experiments; 3939 Mineral Physics: Physical thermodynamics;3919 MineralPhysics:Equationsof state" @default.
- W2127524135 created "2016-06-24" @default.
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- W2127524135 date "2002-07-01" @default.
- W2127524135 modified "2023-10-05" @default.
- W2127524135 title "Direct shock wave loading of Stishovite to 235 GPa: Implications for perovskite stability relative to an oxide assemblage at lower mantle conditions" @default.
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- W2127524135 doi "https://doi.org/10.1029/2002gl015627" @default.
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