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- W2127605890 abstract "The ternary system Ta‐Mo‐C was investigated by X‐ray, melting point, DTA, and metallographic methods on chemically and thermally characterized specimens; a phase diagram for temperatures from 1500°C through the melting range was established. At high temperatures, the cubic monocarbides, TaC and αMOc 1‐x , as well as the hexagonal subcarbides, Ta 2 C and Mo 2 C 3 form continuous series of solid solutions. Below 1960°C, the homogeneity range of the β phase is temperature‐dependent. At 2230°C, the ternary subcarbide solid solution disproportionates into metal and monocarbide alloys. The sub‐lattice order‐disorder transformation temperatures in both subcarbides are lowered by the mutual exchange. The ternary range of the η‐MoC 1‐x , phase is very restricted, and the metastable ζ‐Ta‐C phase is stabilized in the ternary. Seven isothermal reactions occur in the system in the range from melting to 1500°C; two further isotherms between 1400° and 1500°C are indicated to result from the order‐disorder transition in Mo 2 C. Using existing literature data for the thermodynamic properties of the binary carbides, the phase relations in the Ta‐Mo‐C system were thermodynamically analyzed. The calculated equilibria are in good agreement with experimental observations." @default.
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- W2127605890 date "1968-05-01" @default.
- W2127605890 modified "2023-10-09" @default.
- W2127605890 title "Constitution of Ternary Ta-Mo-C Alloys" @default.
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- W2127605890 doi "https://doi.org/10.1111/j.1151-2916.1968.tb13850.x" @default.
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